Complex Chemistry
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Structure and Bonding
Editors: M. J. Clarke, Chestnut Hill • J. B. Goodenough, Oxford J. A. Ibers, Evanston • C. K. J~rgensen, Gen~ve D. M. P. Mingos, Oxford. J. B. Neilands, Berkeley D. Reinen, Marburg • P. J. Sadler, London R. Weiss, Strasbourg • R. J. P. Williams, Oxford
Complex Chemistry
With Contributions by J. Emsley R.D. Ernst B.J. Hathaway K.D. Warren
With 85 Figures and 39 Tables
Springer-Verlag Berlin Heidelberg New York Tokyo 1984
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Professor Michael J. Clarke Boston College, Department of Chemistry, Chestnut Hill, Massachusetts 02167, U.S.A. Professor John B. Goodenough Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, Great Britain Professor James A. Ibers Department of Chemistry, Northwestern University Evanston, Illinois 60201, U.S.A. Professor Christian K. Jcrgensen D~pt. de Chimie Min6rale de l'Universit6, 30 quai Ernest Ansermet, CH-1211 Gen~ve 4 Professor David Michael P. Mingos University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, Great Britain Professor Joe B. Neilands Biochemistry Department, University of California, Berkeley, California 94720, U.S.A. Professor Dirk Reinen Fachbereich Chemie der Philipps-Universittit Marburg, Hans-MeerweinStraBe, D-3550 Marburg Professor Peter J. Sadler Birkbeck College, Department of Chemistry, University of London, London WC1E 7HX, Great Britain Professor Raymond Weiss Institut Le Bel, Laboratoire de CristaUochimie et de Chimie Structurale, 4, rue Blaise Pascal, F-67070 Strasbourg Cedex Professor Robert Joseph P. Williams Wadham College, Inorganic Chemistry Laboratory, Oxford OX1 3QR, Great Britain ISBN 3-540-13411-5 Springer-Verlag Berlin Heidelberg New York Tokyo ISBN 0-387-13411-5 Springer Verlag New York Heidelberg Berlin Tokyo Library of Congress Catalog Card Number 6%11280 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks. Under § 54of the German Copyright Law here copies are made for other than for private use, a fee is payableto "Verwertungsgesellschaft Wort", Munich. © $pringer-Verlag Berlin Heidelberg 1984 Printed in Germany The use of general descriptive names, trade marks, etc. in this publication, even if the former are not especially identified, is not to be taken as a sign that such names, as understood by the Trade Marks and Merchandise Marks Act, may accordingly be used freely by anyone. Typesetting and printing: Schwetzinger Veriagsdruckerei. Bookbinding: J. Schiffer, Grfmstadt. 2152/3140-543210
Table of Contents
Structure and Bonding in Metal-Pentadienyl and Related Compounds R. D. Ernst . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A New Look at the Stereochemistry and Electronic Properties of Complexes of the Copper(II) Ion B. J. Hathaway . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
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