Electronegativity

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Structure and Bonding

Editors: M. J. Clarke, Chestnut Hill J. B. G o o d e n o u g h , Oxford • J. A. Ibers, Evanston C. K. JOrgensen, Gen6ve • D. M. P. Mingos, Oxford J. B. Neilands, Berkeley • G. A. Palmer, Houston D. Reinen, Marburg • P. J. Sadler, L o n d o n R. Weiss, Strasbourg • R. J. P. Williams, Oxford

Electronegativity Editors: K. D. Sen and C. K. JOrgensen

With Contributions by J. A. Alonso L.C. Balb~is L.J. Bartolotti D. Bergmann M. C. B6hm M. Galv~in J.L. G~zquez J. Hinze W. J. Mortier J. Mullay P.C. Schmidt K.D. Sen A.M. Vela

With 39 Figures and 36 Tables

Springer-Verlag Berlin Heidelberg NewYork London Paris Tokyo

Editorial Board

Professor Michael J. Clarke, Boston College, Department of Chemistry, Chestnut Hill, Massachusetts 02167, U.S.A. Professor John B. Goodenough, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, Great Britain Professor James A. Ibers, Department of Chemistry, Northwestern University, Evanston, Illinois 60201, U.S.A. Professor Christian K. JOrgensen, Drpt. de Chimie Minrrale de l'Universitr, 30 quai Ernest Ansermet, CH-1211 Gen~ve 4 Professor David Michael P. Mingos, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, Great Britain Professor Joe B. Neilands, Biochemistry Department, University of California, Berkeley, California 94720, U.S.A. Professor Graham A. Palmer, Rice University, Department of Biochemistry, Wiess School of Natural Sciences, P. O. Box 1892, Houston, Texas 77251, U.S.A. Professor Dirk Reinen, Fachbereich Chemie der Philipps-Universit~it Marburg, Hans-Meerwein-Strage, D-3550 Marburg Professor Peter J. Sadler, Birkbeck College, Department of Chemistry, University of London, London WC1E 7HX, Great Britain Professor Raymond Weiss, Institut Le Bel, Laboratoire de Cristallochimie et de Chimie Structurale, 4, rue Blaise Pascal, F-67070 Strasbourg Cedex Professor Robert Joseph P. Williams, Wadham College, Inorganic Chemistry Laboratory, Oxford OX1 3QR, Great Britain Guest Editor

Professor Kali Das Sen, School of Chemistry, University of Hyderabad, Hyderabad 500134, India ISBN 3-540-17740-X Springer-Verlag Berlin Heidelberg New York ISBN 0-387-17740-X Springer Verlag New York Berlin Heidelberg Library of Congress Cataloging Publication Data. Electronegativity. (Structure and bonding ; 66) Bibliography: p. 1. Electronegativity. I. Sen, K. D. (Kali Das), 1948- . II. JOrgensen, Christian Klixbfill. IIL Alsono, J. A. (Julio A.), 1948- . IV. Series. QD461.$92 Vol. 66 541.2'2 s 87-16401 ISBN 0-387-17740-X (U.S.) [541.2'2] This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned specifically the rights of translation, reprinting, re-use of illustrations, recitation, broadcasting, reproduction on microfilms or in other ways, and storage in data banks. Duplication of this publication or parts thereof is only permitted under the provisions of the German Copyright Law of September 9, 1965, in its version of June 24, 1985, and a copyrigh