EPR Spectroscopy Applications in Chemistry and Biology

Sabine Van Doorslaer Damien M. Murphy EPR Spectroscopy in CatalysisErik Schleicher Stefan Weber Radicals in FlavoproteinsDariush Hinderberger EPR Spectroscopy in Polymer ScienceMalte Drescher EPR in Protein Science Intrinsically Disordered ProteinsEnrica

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Topics in Current Chemistry

Editorial Board: K.N. Houk C.A. Hunter M.J. Krische J.-M. Lehn S.V. Ley M. Olivucci J. Thiem M. Venturi P. Vogel C.-H. Wong H. Wong H. Yamamoto l

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Topics in Current Chemistry Recently Published and Forthcoming Volumes

EPR Spectroscopy: Applications in Chemistry and Biology Volume Editors: Malte Drescher, Gunnar Jeschke Vol. 321, 2012 Radicals in Synthesis III Volume Editors: Markus R. Heinrich, Andreas Gansa¨uer Vol. 320, 2012 Chemistry of Nanocontainers Volume Editors: Markus Albrecht, F. Ekkehardt Hahn Vol. 319, 2012 Liquid Crystals: Materials Design and Self-Assembly Volume Editor: Carsten Tschierske Vol. 318, 2012 Fragment-Based Drug Discovery and X-Ray Crystallography Volume Editors: Thomas G. Davies, Marko Hyvo¨nen Vol. 317, 2012 Novel Sampling Approaches in Higher Dimensional NMR Volume Editors: Martin Billeter, Vladislav Orekhov Vol. 316, 2012 Advanced X-Ray Crystallography Volume Editor: Kari Rissanen Vol. 315, 2012 Pyrethroids: From Chrysanthemum to Modern Industrial Insecticide Volume Editors: Noritada Matsuo, Tatsuya Mori Vol. 314, 2012

Unimolecular and Supramolecular Electronics II Volume Editor: Robert M. Metzger Vol. 313, 2012 Unimolecular and Supramolecular Electronics I Volume Editor: Robert M. Metzger Vol. 312, 2012 Bismuth-Mediated Organic Reactions Volume Editor: Thierry Ollevier Vol. 311, 2012 Peptide-Based Materials Volume Editor: Timothy Deming Vol. 310, 2012 Alkaloid Synthesis Volume Editor: Hans-Joachim Kno¨lker Vol. 309, 2012 Fluorous Chemistry Volume Editor: Istva´n T. Horva´th Vol. 308, 2012 Multiscale Molecular Methods in Applied Chemistry Volume Editors: Barbara Kirchner, Jadran Vrabec Vol. 307, 2012 Solid State NMR Volume Editor: Jerry C. C. Chan Vol. 306, 2012 Prion Proteins Volume Editor: Jo¨rg Tatzelt Vol. 305, 2011 Microfluidics: Technologies and Applications Volume Editor: Bingcheng Lin Vol. 304, 2011 Photocatalysis Volume Editor: Carlo Alberto Bignozzi Vol. 303, 2011

EPR Spectroscopy Applications in Chemistry and Biology Volume Editors: Malte Drescher  Gunnar Jeschke

With Contributions by E. Bordignon  M. Drescher  B. Endeward  D. Hinderberger  I. Krstic´  D. Margraf  A. Marko  D.M. Murphy  T.F. Prisner  E. Schleicher  S. Van Doorslaer  J. van Slageren  S. Weber

Editors Dr. Malte Drescher Department of Chemistry University of Konstanz Konstanz Germany

Dr. Gunnar Jeschke Laboratory of Physical Chemistry ETH Zurich Zurich Switzerland

ISSN 0340-1022 e-ISSN 1436-5049 ISBN 978-3-642-28346-8 e-ISBN 978-3-642-28347-5 DOI 10.1007/978-3-642-28347-5 Springer Heidelberg Dordrecht London New York Library of Congress Control Number: 2012932055 # Springer-Verlag Berlin Heidelberg 2012 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereo