Errata: Activation energy for the reaction of nickel-carbon melts with alumina
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AGOCMe ) and h U,V in many U - V - O s y s t e m s . 2~ But data are r a r e for the activity coefficient of oxygen in t e r n a r y and higher o r d e r alloy s y s t e m s . It is hoped that e x p e r i m e n t a l investigation may be c a r r i e d out to t e s t the validity of Eq. [9] for the m e t a l - o x y g e n systems.
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Fig. 5 - T h e effect of a f o u r t h a l l o y i n g e l e m e n t on the s o l u b i l i t y of nitrogen in stainless steel (Fe-18-Cr-8-Ni) at 1873 K and PN2 = 1 atm; c o m p a r i s o n b e t w e e n the p r e d i c t e d values according to Eq. [9] and the e x p e r i m e n t a l data of Small and Pehlke 2 7 The solid lines are the e x p e r i m e n t a l values and the dashed lines are the p r e d i c t e d values.
e l e m e n t is good. In v i e w of the fact that many of the needed data in utilizing Eq. [9] are e s t i m a t e d v a l u e s , it is s u r p r i s i n g to find good a g r e e m e n t b e t w e e n the p r e d i c t e d and m e a s u r e d v a l u e s . The r e a s o n for the large d i s c r e p a n c y for the effect of Nb in the activity coefficient of N may be due to the i n c o r r e c t v a l u e s of AGN(Nb ) and h U,V p a r a m e t e r s used. It is noteworthy to point out that c o n s i d e r a b l y m o r e r e l i a b l e data are available in the literature for
1. C. B. Alcock and F. D. Richardson: ActaMet., 1958, vol. 6, p. 385. 2. C. B. Alcock and F. D. Richardson: ActaMet., 1960, vol. 8, p. 882. 3. L. S. Darken: Z Am. Chem. Soc., 1950, vol. 72, p. 2909. 4. N. A. Gokcen: Scr. Met., 1969, vol. 3, p. 157, p. 165. 5. G. R. Belton and E. S. Tankins: Trans. TMS-AIME, 1965, vol. 233, p. 1892. 6. U. Block and H. -P.Stiiwe:Z. Metallkd., 1969, vol. 60, p. 766. 7. K. T. Jacob and J. 1t. E. Jeffes: Trans. Inst. Min. Metall., 1971, vol. C80, p. 32. 8. K. T. Jacob and C. B. Alcock: ActaMet., 1972, vol. 20, p. 221. 9. C. Wagner: ActaMet., 1973, vol. 21, pp. 1297-1303. 10. T. Chiang and Y. A. Chang: Met. Trans. B, 1976, vol. 7B, pp. 453-67. 11. J. C. Mathieu, F. Durand, and E. Bonnier: A Chim. Phys., 1965, vol. 62, p. 1289 and p. 1297. 12. B. Brion, J. C. Mathieu, P. Hicter, and P. Desre: J. Chim. Phys., 1970, vol. 66, p. 1238, p. 1745. 13. C. H. P. Lupis and J. F. Elliott: ActaMet., 1967, vol. 15, p. 265. 14. C. H. P. Lupis, H. Gaye, and G. Berard: Scr. Met., 1970, vol. 4, p. 497. 15. E.-Hsin Foo and C. H. P. Lupis: ActaMet., 1973, vol. 21, pp. 1409-30. 16. M. L. Kapoor: Scr. Met., 1976, vol. I0, pp. 323-26. 17. K. Schwerdfeger and W. Pitsch: Project Meeting CALPHAD II, pp. 11 2-1 to 11 2-25, 21-25, June 1976, Max-Planck-Institut ftir Eisenforschung G.m.b.H. Diisseldorf, W. Germany, 1976. 18. R. Y. Lin and Y. A. Chang: Met. Trans. B, 1977, vol. 8B, pp. 293-300. 19. S. Kuo and Y. A. Chang: Met. Trans. B, 1978, vol. 9B, pp. 154-56. 20. Y. A. Chang and D. C. Hu: Met. Trans. B, 1979, vol. 10B, pp. 43-48. 21.
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