Fortschritte Der Chemie Organischer Naturstoffe Progress in the Chem

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L. ZECHMEISTER HERAUSGEGEBEN VON' EDITED BY

W. HERZ

H. GRISEBACH

G. W. KIRBY

TALLAHASSEE, FLA.

FREIBURG i. BR.

GLASGOW

VOL. 30 VERFASSER' AUTHORS

M. J. CORMIER . H. FLASCH . B. FRANCK . K. HOR! . L. JAENICKE W. KELLER-SCHIERLEIN . H. D. LOCKS LEY . D. G. MULLER JUDITH POLONSKY . R. TSCHESCHE . J. E. WAMPLER . G. WULFF

1973 WIEN . SPRINGER-VERLAG' NEW YORK

Mit 28 Abbildungen

With 28 Figures

This work is subject to copyright All rights are reserved, whether the whole or part of the material is concerned, specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks

© 1973 by Springer-VerlagjWien Softcover repl"int of the hardco"el" 1sf edition 1973

Library of Congress Catalog Card Number AC 39-1015

ISB"I-13:978-3-7091-7103-5 DOl: 10.1 007/978-3-7091-71 02-8

e-ISBI\-13:978-3-7091-7102-8

Inhaltsverzeichnis Contents Bioluminescence: Chemical Aspects. By M. J. CORMIER, J. E. WAMPLER, and K. HORI, Department of Biochemistry, University of Georgia, Athens, Georgia, USA ... I. Introduction.......................................................... II. Renilla (Sea Pansy) Bioluminescence. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1. General Comments ................................................. 2. Chemical Requirements for Light Emission ............................ 3. Mechanism of the Light Reaction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4. Related Bioluminescent Systems ..... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..

2 5 5 6 8 14

III. Firefly Bioluminescence ............. , ................................ ,. 1. General Comments ................................................. 2. Chemical Requirements for Light Emission ............................ . 3. Mechanism of the Light Reaction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..

16 16 17 20

IV. Cypridina Bioluminescence. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 1. General Comments ................................................. 2. Chemical Requirements for Light Emission ............................ 3. Mechanism of the Luminescent Reaction. . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 4. Related Bioluminescent Systems ..... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..

26 26 26 28 32

V. Bacterial Bioluminescence. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. J. General Comments ................................................. 2. Chemical Requirements for the Light Reaction. . . . . . . . . . . . . . . . . . . . . . . .. 3. Mechanism of the Light Reaction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..

33 33 34 35

VI. Latia Bioluminescence ................................................. 41 I. General Comments ................................................. 41 2. Chemical Requireme