Lectures on Kinetic Processes in Materials
This book provides beginning graduate or senior-level undergraduate students in materials disciplines with a primer of the fundamental and quantitative ideas on kinetic processes in solid materials. Kinetics is concerned with the rate of change of the sta
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Lectures on Kinetic Processes in Materials
Lectures on Kinetic Processes in Materials
1.40
log aH O= –3.29
¬
–2.75
log a H O= –2.75
¬
σ/10–2Ω–1cm–1
1.35
–3.28
2
1.30 1.25 1.20
2
1.15 –2
0
2
4
6
t × 10–3/s
8
10
Twofold electrical conductivity relaxation upon hydration and reverse dehydration of BaCe0.95Yb0.05O2.975 at 700 C in a fixed oxygen activity atmosphere. (From H.-I. Yoo et al., J. Electrochem. Soc. 156, B66 (2009))
Han-Ill Yoo
Lectures on Kinetic Processes in Materials
Han-Ill Yoo Seoul National University Seoul, South Korea Daegu Gyeongbuk Institute of Science & Technology Daegu, South Korea
ISBN 978-3-030-25949-5 ISBN 978-3-030-25950-1 https://doi.org/10.1007/978-3-030-25950-1
(eBook)
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Dedicated to my mother who passed away on March 1, 2018, and my father
Preface
Thermodynamics teaches us how to describe the state of existence of a system material and in which direction it should change when its state of existence is disturbed by “heat and beat” or “bake and shake.” But it never tells how fast it does; it is kinetics that tells how to describe and evaluate this rate of change. The former may, thus, be regarded as the necessity and the latter as the sufficiency for materials engineering in general, and hence, these two subjects are taught as mandatory courseworks in materials engineering since this discipline was born. Kinetics is, however, notoriously known to be a not-so-easy subject to learn, as much as thermodynamics does, to the students in materials disciplines including the author himself in his student days far back 40 odd years ago. It is often said that therm
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