Microstructure and Texture Evolution During Sub-Transus Thermomechanical Processing of Ti-6Al-4V-0.1B Alloy: Part I. Hot
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UM alloys, owing to their high specific strength, good corrosion properties, and excellent fracture resistance, are known as one of the most important structural materials for aerospace and chemical industries.[1] Most of the titanium alloy products are obtained by casting followed by wrought processing since the ascast titanium alloys possess coarse microstructural features and strong crystallographic texture.[2,3] These two attributes are considered unfavorable for optimal processing; therefore, many attempts have been made to overcome these limitations. Significant success in this regard has been incurred through hypoeutectic boron addition to various titanium alloys, most notably to the (a + b) alloy Ti-6Al-4V.[4–6] The unalloyed microstructure of Ti-6Al-4V consists of a (P63mmc) and b (Im3m) phases wherein the a lamellae form colony structure within prior b grains with the b phase being sandwiched between the a lamellae. Microstructural studies on the cast Ti-6Al-4V alloy containing various levels of boron addition in the
SHIBAYAN ROY, formerly Ph.D. Student with the Department of Materials Engineering, Indian Institute of Science, Bangalore, India, is now Post-doctoral Researcher with the Institut fu¨r Werkstoffwissenschaft und Werkstofftechnik, Chemnitz University of Technology, Chemnitz, Germany. SATYAM SUWAS, Associate Professor, is with the Department of Materials Engineering, Indian Institute of Science. Contact e-mail: [email protected] Manuscript submitted May 31, 2012. Article published online March 15, 2013 METALLURGICAL AND MATERIALS TRANSACTIONS A
hypoeutectic range reveal Widmansta¨tten a colony structure within the prior b grain with significant refinement for both prior b grain and a colony sizes compared with the base alloy without boron.[5] In boron-containing alloys, the TiB phase form as whiskers with aspect ratio ~8 to 9 preferentially at the prior b grain boundaries forming a necklace-like arrangement. Microstructure of the base alloy contains thick grain boundary a layer (~10 lm), whereas the alloy with boron show marked reduction in this micro-constituent size.[6] Godfrey et al.[7] showed significant improvement in tensile strength and ductility, for mechanically alloyed Ti-6Al-4V with hypereutectic boron powder, similar to that expected in wrought Ti-6Al-4V. Zhu et al.,[4] on the other hand, reported that the tensile ductility of cast Ti6Al-4V alloy cannot be improved with hypoeutectic boron addition. A more recent study by Sen et al.[8] showed that with the refinement in the microstructure, the yield and ultimate tensile strengths increase significantly, although ductility drops after 0.1 wt pct boron addition. In-situ tensile testing of a boron-modified Ti6Al-4V alloy at room temperature and 753 K (480 C) revealed higher tensile and ultimate strengths for this alloy with a ductile fracture mode at quasi-static tensile elongations equivalent to conventional Ti-6Al-4V.[9] Elevated temperature (728 K or 455 C) cyclic loading of Ti-6Al-4V-0.1B alloy (wt pct) castings exhibited
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