Nano Focus: Figures of merit developed for conductors in metamaterials and plasmonics
- PDF / 315,615 Bytes
- 2 Pages / 585 x 783 pts Page_size
- 14 Downloads / 173 Views
a
b
T
he interaction between light and surface plasmons in metal nanoparticles allows for interesting new optical materials, provided that the nanoparticles can be arranged in precise architectures. Molecular self-assembly provides a promising method for building such plasmonic structures, as shown by A. Kuzyk from the Technical University of Munich, R. Schreiber from LudwigMaximilians University (Munich), Z. Fan from Ohio University, and their co-workers, who used DNA origami to assemble helices of gold nanoparticles. Their letter in the March 15 issue of Nature (DOI: 10.1038/nature10889; p. 311) describes how these structures interact with polarized light in a similar way to chiral molecules, but at easily tunable wavelengths in the visible spectrum. The rational synthesis of a DNA strand which will fold into a target threedimensional structure, known as DNA origami, was used to provide a scaffold for generating a helical arrangement of nanoparticles. These 16 nm diameter DNA bundles possess nine attachment sites, arranged in one full turn of a 57 nm pitch helix, to which the gold particles (10 nm) were attached by thiol-DNA linkers. Solutions of either all left- or all right-handed helices were then studied using circular dichroism, revealing a difference in absorption between right and left circularly polarized light. As
Nano Focus Figures of merit developed for conductors in metamaterials and plasmonics
R
esearch in metamaterials and plasmonics both involve the study of light in electromagnetic structures. Metamaterials are engineered structures, which are not found in nature, that have an ability to guide light around objects rather than reflecting or refracting it.
(a) Left- and right-handed helices of nine gold nanoparticles that are attached to the surface of a DNA origami structure by thiol-modified DNA linker strands, and (b) a transmission electron microscope image of left-handed gold helices; scale bar 100 nm. Reproduced with permission from Nature 483 (2012), DOI: 10.1038/nature10889; p. 311. ©2012 Macmillan Publishers Ltd.
predicted theoretically, coupling of plasmon waves along the helices results in increased absorption of specific polarizations of light, and left- and right-handed helices show a mirror-image peak/dip close to the surface plasmon resonance frequency at 524 nm. Coating the nanoparticles with a shell of silver (~3 nm thick), which has a shorter wavelength plasmon resonance than gold, unsurprisingly caused a blue shift in the absorption peak. The optical response of the solutions could then be fine-tuned to intermediate absorption frequencies by electroless deposition of a mix of gold and silver, or by mixing helices of different metallic compositions together. The different responses of the left- and right-handed helices could
even be visualized macroscopically by passing linearly polarized white light through droplets of the two solutions, which rotate the polarization in opposite directions. The sample could then be oriented so that red light is transmitted by one solution
Data Loading...
