Solid Base Catalysis

The importance of solid base catalysts has come to be recognized for their environmentally benign qualities, and much significant progress has been made over the past two decades in catalytic materials and solid base-catalyzed reactions. The book is focus

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chemical physics

101

Springer Series in

chemical physics Series Editors: A. W. Castleman, Jr.

J. P. Toennies

K. Yamanouchi

W. Zinth

The purpose of this series is to provide comprehensive up-to-date monographs in both well established disciplines and emerging research areas within the broad f ields of chemical physics and physical chemistry. The books deal with both fundamental science and applications, and may have either a theoretical or an experimental emphasis. They are aimed primarily at researchers and graduate students in chemical physics and related f ields.

Please view available titles in Springer Series in Chemical Physics on series homepage http://www.springer.com/series/676

Yoshio Ono Hideshi Hattori

Solid Base Catalysis

123

Yoshio Ono Professor Emeritus, Tokyo Institute of Technology, Japan E-Mail: [email protected]

Hideshi Hattori Professor Emeritus, Hokkaido University, Japan E-Mail: [email protected]

Series Editors: Professor A.W. Castleman, Jr. Department of Chemistry, The Pennsylvania State University 152 Davey Laboratory, University Park, PA 16802, USA

Professor J.P. Toennies Max-Planck-Institut für Strömungsforschung Bunsenstrasse. 10, 37073 Göttingen, Germany

Professor K. Yamanouchi University of Tokyo, Department of Chemistry Hongo 7-3-1, 113-0033 Tokyo, Japan

Professor W. Zinth Universität München, Institut für Medizinische Optik Öttingerstr. 67, 80538 München, Germany

Springer Series in Chemical Physics

ISSN 0172-6218

ISBN 978-4-7692-0492-3 (Japan) ISBN 978-3-642-18338-6

ISBN 978-3-642-18339-3 (eBook)

DOI 10.1007/978-3-642-18339-3 Springer Heidelberg Dordrecht London New York Library of Congress Control Number: © Springer-Verlag Berlin Heidelberg and Tokyo Institute of Technology Press 2011 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specif ically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction onmicrofilm or in any other way, and storage in data banks.Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer. Violations are liable to prosecution under the German Copyright Law. The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specif ic statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Cover: eStudio Calamar Steinen Printed on acid-free paper 987654321 Springer is a part of Springer Science+Business Media (www.springer.com)

Preface

This volume offers a comprehensive survey of solid base catalysts and their applications to chemical reactions. Fewer efforts have been devoted to solid base catalysis in contrast to the enormous number of studies on the catalysis by solid acids. In 1970, Professor Kozo Tanabe published