Specific Intermolecular Interactions of Element-Organic Compounds
This book extends the development of the thermodynamic theory of specific intermolecular interactions to element-organic and specific organometallic compounds. The fundamentals of an unconventional approach to the theory of H-bonding and specific interact
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Specific Intermolecular Interactions of Element-Organic Compounds
Specific Intermolecular Interactions of Element-Organic Compounds
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Alexei K. Baev
Specific Intermolecular Interactions of Element-Organic Compounds
Alexei K. Baev G.A. Krestov Institute of Solution Chemistry Russian Academy of Sciences Ivanovo Russia
ISBN 978-3-319-08562-3 ISBN 978-3-319-08563-0 (eBook) DOI 10.1007/978-3-319-08563-0 Springer Cham Heidelberg New York Dordrecht London Library of Congress Control Number: 2014953252 © Springer International Publishing Switzerland 2015 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. Exempted from this legal reservation are brief excerpts in connection with reviews or scholarly analysis or material supplied specifically for the purpose of being entered and executed on a computer system, for exclusive use by the purchaser of the work. Duplication of this publication or parts thereof is permitted only under the provisions of the Copyright Law of the Publisher’s location, in its current version, and permission for use must always be obtained from Springer. Permissions for use may be obtained through RightsLink at the Copyright Clearance Center. Violations are liable to prosecution under the respective Copyright Law. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. While the advice and information in this book are believed to be true and accurate at the date of publication, neither the authors nor the editors nor the publisher can accept any legal responsibility for any errors or omissions that may be made. The publisher makes no warranty, express or implied, with respect to the material contained herein. Printed on acid-free paper Springer is part of Springer Science+Business Media (www.springer.com)
Preface
The nonstereotypical ideas concerning the participation of the carbon pentacoordinated atom in the formation of the specific intermolecular interaction with significantly undivided 2s2(с) electron pairs of carbon atoms (DAl ! CH3– Al ¼ 44.2 kJ mol1) have been substantiated and the phenomenon of the intramolecular reverse dative bond between carbon atoms of the methyl group of alkyl ligand and the contacting central molecule atom (in the year 1995) led to the grounded refusal from the model of sp3 hybridization of carbon atoms, proved by the quantum chemical calculations of the methyl compounds of group IV elements. The fourth nonstere
