Spectroscopic Methods in Organic Chemistry
This book is a well-established guide to the interpretation of the mass, ultraviolet, infrared and nuclear magnetic resonance spectra of organic compounds. It is designed for students of organic chemistry taking a course in the application of these techni
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Spectroscopic Methods in Organic Chemistry
Seventh Edition
Spectroscopic Methods in Organic Chemistry
Ian Fleming • Dudley Williams
Spectroscopic Methods in Organic Chemistry Seventh Edition
Ian Fleming Department of Chemistry University of Cambridge Cambridge UK
Dudley Williams Department of Chemistry University of Cambridge Cambridge UK
ISBN 978-3-030-18251-9 ISBN 978-3-030-18252-6 (eBook) https://doi.org/10.1007/978-3-030-18252-6 © Springer Nature Switzerland AG 2019 6 ed 2007, 5 ed 1995, 4 ed 1989, 3rd ed 1980, 2nd 1973, 1st 1966 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors, and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, expressed or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. This Springer imprint is published by the registered company Springer Nature Switzerland AG The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland
Preface
This book is the seventh edition of a well-established introductory guide to the interpretation of the mass, ultraviolet, infrared and nuclear magnetic resonance spectra of organic compounds. It is a textbook suitable for a course in the application of these techniques to structure determination and as a handbook for organic chemists to keep on their desks throughout their career. These four spectroscopic methods are used routinely to determine the structure of organic compounds. Every organic chemist needs to be skilled in how to apply them and to know which method works for which problem. In outline, the mass spectrum gives the molecular formula, the ultraviolet spectrum identifies conjugated systems, the infrared or Raman spectrum identifies functional groups and the nuclear magnetic resonance spectra identify how the atoms are connected. One or more of these techniques are frequently enough to identify the complete chemical structure of an unknown compound. If they are not enough on their own, there are other methods that the organic chemist can turn to: X-ray diffraction, microwave absor
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