Statistical Physics of Polymers An Introduction

This textbook provides senior undergraduate and graduate students with an introduction to the basic concepts used the statistical physics of polymers. Methods of Gaussian chain statistics are discussed in detail. Applications to numerous interesting pheno

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Advanced Texts in Physics This program of advanced texts covers a broad spectrum of topics which are of current and emerging interest in physics. Each book provides a comprehensive and yet accessible introduction to a field at the forefront of modern research. As such, these texts are intended for senior undergraduate and graduate students at the MS and PhD level; however, research scientists seeking an introduction to particular areas of physics will also benefit from the titles in this collection.

Springer-Verlag Berlin Heidelberg GmbH

Toshihiro Kawakatsu

Statistical Physics of Polymers

An Introduction

With 129 Figures

t

Springer

Prof. Toshihiro Kawakatsu Tohoku University Department of Physics Aoba, Aramaki, Aoba-ku Sendai 980-8578, Japan

Cataloging-in-Publication Data. Kawakatsu, Toshihiro. (Kobunshi butsuri no kiso. English) Statistical physics of polymers: an introduction / Toshihiro Kawakatsu. p.cm. - (Advanced texts in physics, ISSN 1439-2674) Includes bibliographical references and index. ISBN 978-3-662-10024-0 (eBook) ISBN 978-3-642-07786-9 DOI 10.1007/978-3-662-10024-0 1. Polymers. 2. Statistical physics. I. Title. II. Series. QC173.4.P65K3913 2004 530.4'29-dc22 2004042943

Original Japanese edition published by Saiensu-Sha Co., Ltd, Tokyo, 2001 ISSN 1439-2674 ISBN 978-3-642-07786-9 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag Berlin Heidelberg GmbH. Violations are liable to prosecution under the German Copyright Law. springeronline.com © Springer-Verlag Berlin Heidelberg 2004 Originally published by Springer-Verlag Berlin Heidelberg New York in 2004 Softcover reprint of tlIe hardcover I st edition 2004

The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesetting: Data prepared by the author using a Springer TEX macro package Cover design: design & production GmbH, Heidelberg Printed on acid-free paper

SPIN 10838845

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5432

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Preface

This book is an introductory textbook on the statistical mechanics of polymers and complex fluids aimed at senior undergraduate and graduate students and non-specialist researchers who are starting research in this field. Modern statistical mechanics on polymers and complex fluids is based on many fields, such as chemical physics, statistical mechanics, quantum mechanics, stochastic processes, theory of phase transitions, hydrodynamics, rheology, and so on. This