The Encapsulation Phenomenon Synthesis, Reactivity and Applications
This fundamental book presents the most comprehensive summary of the current state of the art in the chemistry of cage compounds. It introduces different ways of how ions and molecules can be encapsulated by three-dimensional caging ligands to form molecu
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The Encapsulation Phenomenon Synthesis, Reactivity and Applications of Caged Ions and Molecules
The Encapsulation Phenomenon
Yan Voloshin • Irina Belaya Roland Krämer
The Encapsulation Phenomenon Synthesis, Reactivity and Applications of Caged Ions and Molecules
Yan Voloshin Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences and Gubkin Russian State University of Oil and Gas Moscow Russia
Roland Krämer Anorganisch Chemisches Institut Ruprecht-Karls-Univers. Heidelberg Heidelberg Germany
Irina Belaya Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences Moscow Russia
ISBN 978-3-319-27737-0 ISBN 978-3-319-27738-7 DOI 10.1007/978-3-319-27738-7
(eBook)
Library of Congress Control Number: 2016938266 © Springer International Publishing Switzerland 2016 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer International Publishing AG Switzerland
Y.Z.V. dedicates this book to his beloved son Sasha and daughter Lisa
Preface
Nowadays, a separate realm of modern chemistry is populated by compounds with encapsulated species. Those may be organic and inorganic, anions, cations or neutral molecules that are almost completely isolated from external factors (other ligands, solvents, etc.) by 3D caging (encapsulating) ligands to give molecular and polymeric capsules. The caged species have unique physicochemical properties responsible for specific reactivity and selectivity of their binding and release. The resulting cage complexes may be used for recognition, separation, carrying, storage, and detection of various encapsulated species in the field of molecular and supramolecular devices and modern materials, such as catalysts, carriers of therapeutically active compounds, and many others. Depending on the nature of chemical or supramolecular bonds between precursors (ligand syntones, some of them are shown in italic) o
