The Metal-Hydrogen System Basic Bulk Properties

Metal hydrides are of inestimable importance for the future of hydrogen energy. This unique monograph presents a clear and comprehensive description of the bulk properties of the metal-hydrogen system. The statistical thermodynamics is treated over a very

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materials science

21

Springer Series in

materials science Editors: R. Hull

R. M. Osgood, Jr.

J. Parisi

H. Warlimont

The Springer Series in Materials Science covers the complete spectrum of materials physics, including fundamental principles, physical properties, materials theory and design. Recognizing the increasing importance of materials science in future device technologies, the book titles in this series ref lect the state-of-the-art in understanding and controlling the structure and properties of all important classes of materials. 71 Dissipative Phenomena in Condensed Matter Some Applications By S. Dattagupta and S. Puri

79 Magnetism and Structure in Functional Materials Editors: A. Planes, L. Man˜osa, and A. Saxena

72 Predictive Simulation of Semiconductor Processing Status and Challenges Editors: J. Dabrowski and E.R. Weber

80 Ion Implantation and Synthesis of Materials By M. Nastasi and J.W. Mayer

73 SiC Power Materials Devices and Applications Editor: Z.C. Feng 74 Plastic Deformation in Nanocrystalline Materials By M.Yu. Gutkin and I.A. Ovid’ko 75 Wafer Bonding Applications and Technology Editors: M. Alexe and U. G¨osele 76 Spirally Anisotropic Composites By G.E. Freger, V.N. Kestelman, and D.G. Freger 77 Impurities Confined in Quantum Structures By P.O. Holtz and Q.X. Zhao 78 Macromolecular Nanostructured Materials Editors: N. Ueyama and A. Harada

81 Metallopolymer Nanocomposites By A.D. Pomogailo and V.N. Kestelman 82 Plastics for Corrosion Inhibition By V.A. Goldade, L.S. Pinchuk, A.V. Makarevich and V.N. Kestelman 83 Spectroscopic Properties of Rare Earths in Optical Materials Editors: G. Liu and B. Jacquier 84 Hartree–Fock–Slater Method for Materials Science The DV–X Alpha Method for Design and Characterization of Materials Editors: H. Adachi, T. Mukoyama, and J. Kawai 85 Lifetime Spectroscopy A Method of Defect Characterization in Silicon for Photovoltaic Applications By S. Rein 86 Wide-Gap Chalcopyrites Editors: S. Siebentritt and U. Rau

Volumes 20–70 are listed at the end of the book.

Y. Fukai

The Metal–Hydrogen System Basic Bulk Properties

Second, Revised and Updated Edition

With 287 Figures and 55 Tables

123

Professor Yuh Fukai, D.Sc. Chuo University Department of Physics Kasuga, Bunkyo-ku, Tokyo 112., Japan E-mail: [email protected]

Series Editors:

Professor Robert Hull

Professor Jürgen Parisi

University of Virginia Dept. of Materials Science and Engineering Thornton Hall Charlottesville, VA 22903-2442, USA

Universit¨at Oldenburg, Fachbereich Physik Abt. Energie- und Halbleiterforschung Carl-von-Ossietzky-Strasse 9–11 26129 Oldenburg, Germany

Professor R. M. Osgood, Jr.

Professor Hans Warlimont

Microelectronics Science Laboratory Department of Electrical Engineering Columbia University Seeley W. Mudd Building New York, NY 10027, USA

Institut f¨ur Festk¨orperund Werkstofforschung, Helmholtzstrasse 20 01069 Dresden, Germany

ISSN 0933-033X ISBN-10 3-540-00494-7 Springer Berlin Heidelberg New York ISBN-13 978-3-540-00494-3 Springer Berlin Heidelberg New York Li