Thermodynamics and Fluctuations far from Equilibrium
This book deals with the formulation of the thermodynamics of chemical and other systems far from equilibrium, including connections to fluctuations. It contains applications to non-equilibrium stationary states and approaches to such states, systems with
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chemical physics
90
Springer Series in
chemical physics Series Editors: A. W. Castleman, Jr.
J. P. Toennies
K. Yamanouchi
W. Zinth
The purpose of this series is to provide comprehensive up-to-date monographs in both well established disciplines and emerging research areas within the broad f ields of chemical physics and physical chemistry. The books deal with both fundamental science and applications, and may have either a theoretical or an experimental emphasis. They are aimed primarily at researchers and graduate students in chemical physics and related f ields. 75 Basic Principles in Applied Catalysis By M. Baerns 76 The Chemical Bond A Fundamental Quantum-Mechanical Picture By T. Shida 77 Heterogeneous Kinetics Theory of Ziegler-Natta-Kaminsky Polymerization By T. Keii 78 Nuclear Fusion Research Understanding Plasma-Surface Interactions Editors: R.E.H. Clark and D.H. Reiter 79 Ultrafast Phenomena XIV Editors: T. Kobayashi, T. Okada, T. Kobayashi, K.A. Nelson, and S. De Silvestri 80 X-Ray Diffraction by Macromolecules By N. Kasai and M. Kakudo 81 Advanced Time-Correlated Single Photon Counting Techniques By W. Becker 82 Transport Coefficients of Fluids By B.C. Eu 83 Quantum Dynamics of Complex Molecular Systems Editors: D.A. Micha and I. Burghardt
84 Progress in Ultrafast Intense Laser Science I Editors: K. Yamanouchi, S.L. Chin, P. Agostini, and G. Ferrante 85 Quantum Dynamics Intense Laser Science II Editors: K. Yamanouchi, S.L. Chin, P. Agostini, and G. Ferrante 86 Free Energy Calculations Theory and Applications in Chemistry and Biology Editors: Ch. Chipot and A. Pohorille 87 Analysis and Control of Ultrafast Photoinduced Reactions Editors: O. K¨uhn and L. W¨oste 88 Ultrafast Phenomena XV Editors: P. Corkum, D. Jonas, D. Miller, and A.M. Weiner 89 Progress in Ultrafast Intense Laser Science III Editors: K. Yamanouchi, S.L. Chin, P. Agostini, and F. Ferrante 90 Thermodynamics and Fluctuations far from Equilibrium By J. Ross
John Ross
Thermodynamics and Fluctuations far from Equilibrium With a Contribution by R.S. Berry With 74 Figures
123
Professor Dr. John Ross Stanford University, Department of Chemistry 333, Campus Drive, Stanford, CA 94305-5080, USA E-Mail: [email protected]
Contributor:
Professor Dr. R.S. Berry University of Chicago, Department of Chemistry and the James Franck Institute 5735, South Ellis Avenue, Chicago, IL 60637, USA E-Mail: [email protected]
Series Editors:
Professor A.W. Castleman, Jr. Department of Chemistry, The Pennsylvania State University 152 Davey Laboratory, University Park, PA 16802, USA
Professor J.P. Toennies Max-Planck-Institut f¨ur Str¨omungsforschung Bunsenstrasse 10, 37073 G¨ottingen, Germany
Professor K. Yamanouchi University of Tokyo, Department of Chemistry Hongo 7-3-1, 113-0033 Tokyo, Japan
Professor W. Zinth Universit¨at M¨unchen, Institut f¨ur Medizinische Optik ¨ Ottingerstr. 67, 80538 M¨unchen, Germany
ISSN 0172-6218 ISBN 978-3-540-74554-9 Springer Berlin Heidelberg New York Library of Congress Control Number: 2007938639 This work is
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