Transformation of Carbon Dioxide to Formic Acid and Methanol
This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basi
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Wan-Hui Wang Xiujuan Feng Ming Bao
Transformation of Carbon Dioxide to Formic Acid and Methanol
123
SpringerBriefs in Molecular Science Green Chemistry for Sustainability
Series editor Sanjay K. Sharma, Jaipur, India
More information about this series at http://www.springer.com/series/10045
Wan-Hui Wang Xiujuan Feng Ming Bao •
Transformation of Carbon Dioxide to Formic Acid and Methanol
123
Wan-Hui Wang School of Petroleum and Chemical Engineering Dalian University of Technology Panjin, Liaoning China
Ming Bao Dalian University of Technology Dalian, Liaoning China
Xiujuan Feng Dalian University of Technology Dalian, Liaoning China
ISSN 2191-5407 ISSN 2191-5415 (electronic) SpringerBriefs in Molecular Science ISSN 2212-9898 ISSN 2452-185X (electronic) SpringerBriefs in Green Chemistry for Sustainability ISBN 978-981-10-3249-3 ISBN 978-981-10-3250-9 (eBook) https://doi.org/10.1007/978-981-10-3250-9 Library of Congress Control Number: 2017956307 © The Author(s) 2018 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer Nature Singapore Pte Ltd. The registered company address is: 152 Beach Road, #21-01/04 Gateway East, Singapore 189721, Singapore
Contents
1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Transformation of CO2 to Formic Acid or Formate with Homogeneous Catalysts . . . . . . . . . . . . . . . . . . . . 2.1 CO2 Hydrogenation Using Noble Metals . . . . . . . . 2.1.1 Ruthenium Complexes . . . . . . . . . . . . . . . . 2.1.2 Rhodium Complexes . . . . . . . . . . . . . . . . . 2.1.3 Iridium Complexes . . . . . . . . . . . . . . . . . . 2.2 CO2 Hydrogenation Using Non-precious Meta
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