2D electrocatalytic MOF sets efficiency record for water splitting
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Stretch goals: Elastic conductors reach a new milestone
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ensitive elastic conductive materials that can withstand high strains due to stretching are critical for next-generation wearable devices and robotics. Printable elastic conductors are promising candidates for generating large-area, stretchable sensor/actuator networks. These conductors are typically composite materials comprising elastomers laced with metal nanoparticles. Although these composites can deliver high performance, their widespread use has been hampered by various processing challenges. Now, researchers at The University of Tokyo have fabricated a new elastic composite material that retains its high conductivity even when stretched to five times its original length. This new material is made by printing an ink containing fluorine rubber, fluorine surfactant, silver flakes, and methylisobutylketone as the solvent. It can be printed in various patterns on textiles and rubber surfaces, and can be used as stretchable wiring for wearable devices with sensors. Remarkably, the silver flakes—which are used as a low-cost conducting filler—transform into silver nanoparticles upon printing and heating of the ink (temperatures between 80°C and 150°C were studied). Electron microscopy revealed silver nanoparticles between two and ten nanometers in diameter, about 1000 times smaller than the original flakes. “We did not expect the formation of Ag nanoparticles,” says lead researcher Takao Someya. As reported in Nature Materials (doi:10.1038/NMAT4904), these printable
2D electrocatalytic MOF sets efficiency record for water splitting
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two-dimensional nickel/iron metal– organic framework (2D NiFeMOF), fabricated by researchers at the University of New South Wales in Sydney, Australia, has established a
elastic composites exhibit conductivity higher than 4000 S cm−1 at 0% strain, and 935 S cm−1 when stretched up to 400%—the highest conductivity reported to date for this amount of stretching. The high performance of the conductor resulted from self-formation of silver nanoparticles one-thousandth the size of the Ag flakes that were formed after the conductive composite paste was printed and heated. The researchers say that the in situ formation of silver nanoparticles in the elastomer matrix improves the conductivity due to enhanced percolation between the silver A new elastic composite conductor demonstrates high conductivity that is maintained even while the material is stretched. flakes and the suppression For example, a light-emitting diode (top) continues to shine of crack formation through brightly even when stretched to five times its original length nanoparticle reinforcement. (bottom). Courtesy of Takao Someya, The University of Tokyo. Furthermore, by adjusting the molecular weight of the fluorine rubber, the team could control the distribution and popuThis is enough to accommodate highlation of nanoparticles, while the surfacstress flexible areas, such as elbows and tant and heating accelerated particle forknees on conformable, form-fitting mation
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