Appraising different models for predicting biomethane potential: the case of avocado oil processing by-products

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Appraising different models for predicting biomethane potential: the case of avocado oil processing by‑products Charles Rashama1   · Grace N. Ijoma1 · Tonderayi S. Matambo1 Received: 27 May 2020 / Accepted: 11 September 2020 © Springer Japan KK, part of Springer Nature 2020

Abstract Biomethane potentials (BMPs) for avocado oil processing by-products were determined using six different theoretical BMP prediction models and results were compared with empirical values found in literature. The by-products were classified as kernels, skins, decanter pomace and decanter wastewater prior to physicochemical characterisation and BMP calculation of individual by-products. The estimated BMP values for the different by-products ranged between 152 and 889 m ­ LCH4/gVS using the different prediction models across substrates. These values compare favourably with biomethane potentials for popular biogas plant substrates such as cow manure and food waste-based floatable oil whose biomethane potentials are 150 and 847 ­mLCH4/gVS, respectively. Results from the nutritional based and statistically derived canonical mixtures theoretical BMP prediction models for kernels (289 ­mLCH4/gVS) closely matched empirical values (284 ­mLCH4/gVS) from literature. We conclude that anaerobic digestion for biogas production can be preliminarily considered as a viable waste-to-energy technology option for managing avocado oil processing by-products. The statistically derived (nutritional based) theoretical BMP prediction models offer the best approach for evaluating these substrates’ candidature for biomethane production. Keywords  Avocado waste · Biomethane potential · Biogas · Waste management · Prediction models

Introduction The avocado oil processing industry is growing rapidly having recorded more than a 700% increase over an 8 year period from the 2009 oil production figures of 2,000–16,000 t in 2017 [1, 2]. This industrial growth, however, also comes with increased waste by-products generation in the form of skins, kernel, pomace and wastewater. Based on projected oil production estimates [3] as well as mass balances for avocado oil extraction processes, [4] approximately 170,000 t per annum by-products wastes production rates will be recorded in 2025. South Africa’s current annual generation of avocado oil processing waste by-products stands at approximately 11,000 t per annum. These organics rich byproduct wastes are currently disposed through landfilling or as soil amendments on the avocado groves with the liquid * Charles Rashama [email protected] 1



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portion normally being treated in oxidation ponds before use as irrigation liquid on the same fields [4]. These waste management practices take up productive land space, contribute to the uncontrolled methane emissions from landfills, result in possible toxic leachates from landfills/lagoons seep