Atoms, Molecules and Photons An Introduction to Atomic-, Molecular-

This introduction to Atomic and Molecular Physics explains how our present model of atoms and molecules has been developed over the last two centuries both by many experimental discoveries and, from the theoretical side, by the introduction of quantum phy

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Wolfgang Demtröder

Atoms, Molecules and Photons An Introduction to Atomic-, Molecularand Quantum-Physics

With 663 Figures and 43 Tables

123

Professor Dr. Wolfgang Demtröder University Kaiserslautern Department of Physics 67663 Kaiserslautern, Germany e-mail: [email protected] or [email protected] URL: http://www.physik.uni-kl.de/w_demtro/w_demtro.html

ISBN-10 3-540-20631-0 ISBN-13 978-3-540-20631-6 Springer Berlin Heidelberg New York Library of Congress Number: 2005936509

This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer. Violations are liable for prosecution under the German Copyright Law. Springer is a part of Springer Science+Business Media springer.com c Springer-Verlag Berlin Heidelberg 2006  Printed in Germany The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesetting, Illustrations and Production: LE-TeX Jelonek, Schmidt & Vöckler GbR, Leipzig, Germany Cover design: eStudio calamar, Frido Steinen-Broo, Spain Printing and binding: Stürtz GmbH, Würzburg, Germany Printed on acid-free paper 56/3141/YL - 5 4 3 2 1 0

Preface

The detailed understanding of matter, its phase transitions and its interaction with radiation could be only reached, after its microscopic structure determined by the kind of atoms or molecules as basic constituents of matter had been investigated. This knowledge allowed the controlled optimization of characteristic properties of matter. Atomic physics therefore represents not only an area of important fundamental research, but has furthermore many applications which have essentially formed our present technical world. The understanding of materials and their use in daily life, has major impact of our culture and our attitude towards nature and our environment. This textbook is aimed as an introduction to the microscopic world of atoms, molecules and photons. It illustrates how our knowledge about the microscopic structure of matter and radiation came about and which crucial experiments forced an extension and refinement of existing classical theories, culminating in the development of quantum theory, which is now accepted as the basic theory of atomic and molecular physics. The book therefore starts with a short historical review about the role of experiments for correcting erroneous ideas and proving the existence of atoms and molecules. The close interaction between experiments and theory has b