Bond and Structure Models

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J.C. Hawes

Complementary Spherical Electron Density Model J. C.A. Boeyens Molecular Mechanics and the Structure Hypothesis S.-C. Tam R.J.P. Williams Electrostatics and Biological Systems K. Nag

S.N. Bose

Chemistry of Tetra- and Pentavalent Chromium

Bond and Structure M o d e l s Springer-Verlag Berlin Heidelberg New York Tokyo

63

Structure and Bonding

Editors: M. J. Clarke, Chestnut Hill J. B. Goodenough, Oxford 9 J. A. Ibers, Evanston C. K. J#rgensen, Gen6ve 9 D. M. P. Mingos, Oxford J. B. Neilands, Berkeley 9 G. A. Palmer, Houston D. Reinen, Marburg 9 P. J. Sadler, London R. Weiss, Strasbourg 9 R. J. P. Williams, Oxford

Bond and Structure Models

With Contributions by J. C. A. Boeyens S.N. Bose J.C. Hawes D. M. P. Mingos K. Nag S.-C. Tam R. J. P. Williams With 66 Figures and 39 Tables

Springer-Verlag Berlin Heidelberg New York Tokyo

Editorial Board

Professor Michael J. Clarke, Boston College, Department of Chemistry, Chestnut Hill, Massachusetts 02167, U.S.A. Professor John B. Goodenough, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, Great Britain Professor James A. Ibers, Department of Chemistry, Northwestern University, Evanston, Illinois 60201, U.S.A. Professor Christian K. Jorgensen, Ddpt. de Chimie Mindrale de l'Univcrsit6, 30 quai Ernest Ansermet, CH-1211 Gen~ve 4 Professor David Michael P. Mingos, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, Great Britain Professor Joe B. Neilands, Biochemistry Department, University of California, Berkeley, California 94720, U.S.A. Professor Graham A. Palmer, Rice University, Department of Biochemistry, Wiess School of Natural Sciences, P. O. Box 1892, Houston, Texas 77251, U.S.A. Professor Dirk Reinen, Fachbereich Chemie der Philipps-Universit~it Marburg, Hans-Meerwein-StraBe, D-3550 Marburg Professor PeterJ. Sadler, Birkbeck College, Department of Chemistry, University of London, London WC1E 7HX, Great Britain Professor Raymond Weiss, Institut Le Bel, Laboratoire de Cristallochimie et de Chimie Structurale, 4, rue Blaise Pascal, F-67070 S~rasbourg Cedex Professor Robert Joseph P. Williams, Wadham College, Inorganic Chemistry Laboratory, Oxford OXI 3OR, Great Britain

ISBN 3-540-15820-0 Springer-Verlag Berlin Heidelberg New York Tokyo ISBN 0-387-15820-0 Springer Verlag New York Heidelberg Berlin Tokyo

Library of Congress Catalog Card Number 67-11280 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks. Under w 54 of the German Copyright Law here copies are made for other than for private use, a fee is payable to "Verwertungsgesellschaft Wort", Munich. 9 Springer-Verlag Berlin Heidelberg 1985 Printed in Germany The use of general descriptive names, trade marks, etc. in this publication, even if the former are not especially identified, is not to be