Cage Metal Complexes Clathrochelates Revisited
This fundamental book presents the most comprehensive summary of the current state in chemistry of cage metal complexes. After their previous book “The Encapsulation Phenomenon” (ISBN 978-3-319-27737-0) the authors in this book focus on the enca
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Metal Complexes Clathrochelates Revisited
Cage Metal Complexes
Yan Voloshin • Irina Belaya • Roland Kra¨mer
Cage Metal Complexes Clathrochelates Revisited
Yan Voloshin Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences Moscow, Russia
Irina Belaya Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences Moscow, Russia
Gubkin Russian State University of Oil and Gas Moscow, Russia Roland Kra¨mer Anorganisch Chemisches Institut Ruprecht-Karls-Universita¨t Heidelberg Heidelberg, Germany
ISBN 978-3-319-56419-7 ISBN 978-3-319-56420-3 (eBook) DOI 10.1007/978-3-319-56420-3 Library of Congress Control Number: 2017940403 # Springer International Publishing AG 2017 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer International Publishing AG The registered company address is: Gewerbestrasse 11, 6330 Cham, Switzerland
Preface
Compounds with encapsulated species were found to have unique chemical, physical, and physicochemical properties. Those that contain organic ions, nonmetal inorganic cations, and neutral molecules as guests have been proposed for the efficient recognition, separation, carrying, storage, and detection of various encapsulated caged species, thus entering the field of molecular and supramolecular devices and modern material. Those include efficient catalysts, carriers of therapeutically active compounds, and many others; main results in these fields have been recently summarized in our book “The encapsulation phenomenon—synthesis, reactivity and applications of caged ions and molecules,” 2016 [1]. On the other hand, the encapsulation of metal cations has been skipped in the above book; the situation in this field, as it appeared before 2002, has been highlighted in the monograph “C
