Chemistry of Thioamides
This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of h
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emistry of Thioamides
Chemistry of Thioamides
Toshiaki Murai Editor
Chemistry of Thioamides
123
Editor Toshiaki Murai Gifu University Gifu, Japan
ISBN 978-981-13-7827-0 ISBN 978-981-13-7828-7 https://doi.org/10.1007/978-981-13-7828-7
(eBook)
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Preface
I have been involved in the development of synthetic methods and new reactions using thioamides for about 20 years. On the basis of the teaching that it is not necessary to stay in a busy place from the beginning when we start new research in the fields of synthetic chemistry, at first I hesitated to start that chemistry. Until then, I had studied compounds involving selenium and tellurium atoms, which are heavier elements of the sulfur atom in the Periodic Table. A limited number of researchers were engaged in selenium and tellurium chemistry, and there was a high possibility that the originality of our own research was guaranteed. In those studies, one of graduate students in the laboratory discovered that new active chemical species were generated from selenoamides, which was a selenium analogue of amides, and the carbon–carbon bond-forming reaction using those was achieved. I thought we could provide new synthetic chemistry with those reactions. However, handling of organoselenium compounds are generally non-trivial. So I decided to start research based on thioamides, whose rich chemistry has already been reported even at that time. Therefore, we had to be very careful to see if similar reactions were already reported or not. Fortunately, even in those situations, we encountered several novel synthetic reactions. A few
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