Contaminated Rivers A Geomorphological-Geochemical Approach to Site
The geomorphological, surficial and geochemical processes and conditions of rivers require a tailored set of strategies and programs to successfully clean up contaminated river reaches. The primary purpose of this book is not only to provide students and
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Contaminated Rivers A Geomorphological-Geochemical Approach to Site Assessment and Remediation
By
Jerry R. Miller Department of Geosciences & Natural Resources Management, Western Carolina University, NC, USA
and
Suzanne M. Orbock Miller Haywood County Schools, NC, USA
A C.I.P. Catalogue record for this book is available from the Library of Congress.
ISBN-10 ISBN-13 ISBN-10 ISBN-13
1-4020-5286-3 (HB) 978-1-4020-5286-6 (HB) 1-4020-5602-8 (e-book) 978-1-4020-5602-4 (e-book)
Published by Springer, P.O. Box 17, 3300 AA Dordrecht, The Netherlands. www.springer.com
Printed on acid-free paper
All Rights Reserved © 2007 Springer No part of this work may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, microfilming, recording or otherwise, without written permission from the Publisher, with the exception of any material supplied specifically for the purpose of being entered and executed on a computer system, for exclusive use by the purchaser of the work.
To Mary and Rebecca
TABLE OF CONTENTS
Preface 1.
2.
3.
xiii
Contaminated Rivers: An Overview 1.1. Introduction 1.2. Types of Contaminants 1.2.1. Organic Contaminants 1.2.2. Inorganic Contaminants 1.3. National Assessments of River Health 1.3.1. The National Water Quality Inventory 1.3.2. The National Sediment Quality Survey 1.3.3. The National Water-Quality Assessment Program 1.3.4. Sources of Contamination 1.4. The Dissolved Versus Particulate Load 1.5. Site Characterization, Assessment, and Remediation 1.6. The Geomorphological-Geochemical Approach 1.7. Summary 1.8. Suggested Readings
1 1 3 3 8 11 12 14 17 18 21 23 27 30 31
Sediment-Trace Metal Interactions 2.1. Introduction 2.2. Physical Partitioning of Trace Metals in Sediment 2.3. Chemical Partitioning of Trace Elements in Sediment 2.3.1. Mechanistic Associations 2.3.2. Chemically Reactive Substrates 2.4. Elemental Speciation 2.5. Chemical Remobilization 2.6. Summary 2.7. Suggested Readings
33 33 34
Basin Processes 3.1. Introduction
69 69 vii
39 39 53 60 63 66 67
viii
Table of Contents 3.2.
3.3.
3.4.
3.5. 3.6. 4.
5.
Hillslope Hydrology 3.2.1. Direct Runoff Generation 3.2.2. Flood Hydrographs Contaminant Transport Pathways 3.3.1. The Controlling Factors 3.3.2. Transport via Hortonian Overland Flow 3.3.3. Mapping Spatial Variations in Metal Sources Hillslope Erosion 3.4.1. Basic Mechanics 3.4.2. Measurement of Erosion Rates 3.4.3. Prediction of Erosion Rates Summary Suggested Readings
The Water Column – Concentration and Load 4.1. Introduction 4.2. Temporal Variations in Concentration 4.2.1. Dissolved Constituents 4.2.2. Particulate and Particulate-Borne Contaminant Concentrations 4.3. Sediment and Contaminant Loads 4.3.1. Load Estimation 4.3.2. The Effective Transporting Discharge 4.4. Summary 4.5. Suggested Readings The Channel Bed – Contaminant Transport and Storage 5.1. Introduction 5.2. Sediment Transport 5.2.1. Modes of Transport 5.2.2. Channelized Flow 5.2.3. Entrainment 5.3. Processes of Contaminant
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