Dehydration of rhyolite: activation energy, water speciation and morphological investigation
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Dehydration of rhyolite: activation energy, water speciation and morphological investigation Panagiotis M. Angelopoulos1 · Nebojša Manić2 · Petros Tsakiridis3 · Maria Taxiarchou1 · Bojan Janković4 Received: 3 March 2020 / Accepted: 21 July 2020 © Akadémiai Kiadó, Budapest, Hungary 2020
Abstract Rhyolite is an extrusive, igneous rock of aluminosilicate composition that upon rapid cooling forms obsidian. Obsidian is amorphous and contains limited water portions ( 5 mass%). In the current study, kinetics of hydrous rhyolite dehydration were investigated by thermogravimetry up to 1000 °C, at heating rates of 2.5, 5, 10 and 20 °C min−1 and under inert atmosphere. The mass loss is approx. 7.6 mass%, occurs along wide temperature range (100–800 °C) and is solely attributed to the release of molecular water ((H2O)m) and hydroxyl groups (OH). Rhyolite dehydration was considered as a solid-state reaction, and the apparent activation energy ( Ea) of dehydration was calculated throughout the whole conversion range (a) by applying the isoconversional Friedman and advanced Vyazovkin methods. Both methods revealed inverse sigmoid trend in Ea values versus conversion degree, possessing almost stable value of 61 ± 5 kJ mol−1 for Friedman method and 59.44 kJ mol−1 for Vyazovkin method on conversion range between 0.25 and 0.75, and sharp increase at higher conversion degree. The intensive change in Ea during dehydration progression is attributed to the change in releasing species (from (H2O)m to OH). Raman and FT-IR spectroscopy analyses of raw and partially dehydrated samples at different stages revealed that up to 300 °C mainly (H2O)m is diffused out of the material causing sample enrichment in OH groups. OH release, which occurs at relatively higher temperature, is accompanied by increase in apparent Ea value of dehydration. Concerning microstructure of raw rhyolite, it exhibits a network of micro-fractures which serve as water release routes. Upon heating, more and wider fractures are created. At 600 °C, fractures merging occurs creating voids, which constitute forerunners of the expansion phenomenon. Further temperature increase causes material softening allowing local plastic deformation, which under the high pressure that is exerted by the releasing water species incites the formation of large cavities and fractures, initiating expansion. Keywords Hydrous rhyolite · Isoconversional methods · Expanded perlite · Volcanic glass dehydration · Dehydroxylation · Activation energy
Introduction * Panagiotis M. Angelopoulos [email protected] 1
Laboratory of Metallurgy, School of Mining and Metallurgical Engineering, National Technical University of Athens, 9 Heroon Polytechniou St, 15780 Athens, Greece
2
Fuel and Combustion Laboratory, Faculty of Mechanical Engineering, University of Belgrade, 16 Kraljice Marije St, P.O. Box 35, Belgrade 11120, Serbia
3
Laboratory of Physical Metallurgy, School of Mining and Metallurgical Engineering, National Technical University of Athens, 9 Heroon Polytechniou St, 1578
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