Effect of Nanosilica and Nanoclay on the Mechanical, Physical, and Morphological Properties of Recycled Linear Low Densi

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ORIGINAL PAPER

Effect of Nanosilica and Nanoclay on the Mechanical, Physical, and Morphological Properties of Recycled Linear Low Density Polyethylene/Rice Husk Composites Wagih Abdel  Alim Sadik1 · Abdel  Ghaffar Maghraby El Demerdash1 · Rafik Abbas1 · Alaa Bedir1  Accepted: 19 November 2020 © Springer Science+Business Media, LLC, part of Springer Nature 2020

Abstract The principal objective of this study was to assess the capability of waste rice husk fibers as reinforcement for recycled plastics. The fabrication of Wood-plastic composites (WPCs) based on rice husk (RH) fibers and recycled linear low polyethylene in the presence of maleic anhydride grafted polyethylene (3 phc) were made by melt blending method. The impact of nanosilica and nanocaly, at different concentrations (2, 4, and 6 phc) on morphological, physical–mechanical and thermal properties of the prepared WPCs were studied to distinguish the most efficient nanoparticle. The highest improvement of mechanical properties was achieved at 6phc nanosilica loading and 4phc nanoclay. At a high level of nanoclay loading (6phc), increased population of clay pellets leads to agglomeration, and stress transfer gets blocked. Izod impact strength was decreased by the incorporation of different nanoparticles in contrast with the hardness. The addition of different nanoparticles decreased the water absorption and thickness swelling of composites. The interaction of the rice husk fibers with the polymer matrix as well as the impact of nanosilica and nanoclay in the improvement of the adhesion was shown by scanning electron microscopy (SEM). In addition, the thermal stability showed slightly improved by the addition of nanoparticles, but there are no perceptible changes in the values of melting temperature by increasing the nanosilica and nanoclay content. The degree of crystallinity ­(Xc) of the composites decreased with the incorporation of RH fibers and increased with the addition of nanoparticles. The finding demonstrated that WPCs treated by nanosilica had the most elevated properties than nanoclay. Keywords  Recycled plastic · Rice husk · Nanosilica · Nanoclay · Wood-plastic composites

Introduction In recent times, nanoparticles and natural fibers have been increasing consideration in the fabrication of composite because of two causes. The first is to promote the properties of the composites by including nanoparticle. The second is * Alaa Bedir [email protected] Wagih Abdel Alim Sadik [email protected] Abdel Ghaffar Maghraby El Demerdash [email protected] Rafik Abbas [email protected] 1



Department of Materials Science, Institute of Graduate Studies and Research, Alexandria University, 163 Horreya Avenue, Alshatby, Alexandria 21526, Egypt

to evolve eco-friendly materials by using cellulose fibers as an alternative to advanced fibers in wood-plastic composites [1]. Reinforcing plastics with natural fibers has got numerous attractions mainly because of mechanical improvement that can be acquired at a relatively low cost [2]. Wood-polymer