Effect of Nonionic Conjugated Matrix Polymer and P-Dopant on Carbon Nanotube Aggregation and Thermoelectric Properties

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MRS Advances © 2018 Materials Research Society DOI: 10.1557/adv.2018.563

Effect of Nonionic Conjugated Matrix Polymer and P-Dopant on Carbon Nanotube Aggregation and Thermoelectric Properties Hui Li1, Jiyuan Huang1, Toshiyuki Sato2, Paul Czubarow3, and Howard E. Katz1* 1

Department of Materials Science and Engineering, Johns Hopkins University, 206 Maryland Hall, 3400 North Charles Street, Baltimore, MD 21218

2

NAMICS Corporation, NTC, 3993 Nigorikawa, Kita-ku, Niigata-City, Japan 950-3131

3

eM-TECH, Inc., 200 Turnpike Rd. Suite 3, Southborough, MA 01772

*Corresponding author: [email protected]

ABSTRACT

The properties of a mixed metallic and semiconducting carbon nanotube (CNT) sample dispersed in nonconjugated poly(methyl methacrylate) (PMMA) and conjugated poly(bisdodecylquaterthiophene) (PQT12) were compared, with and without p-doping by NOBF4. The CNTs were distributed much more evenly, and percolated at much lower concentrations (ca. 2%), in the PMMA as compared to PQT12, as judged by optical microscopy and electronic conductivity measurements. Seebeck coefficients (S) obtained on the PMMA samples indicated dominance by the metallic fraction, with values