Effects of Particle Size on the NO 2 Gas Sensing Properties of NiO Nanoparticle-Decorated SnO 2 Nanorods
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Effects of Particle Size on the NO2 Gas Sensing Properties of NiO Nanoparticle-Decorated SnO2 Nanorods Kyeongbin Choi, Gyujin Jeong, Soong Keun Hyun, Bumhee Nam, Tae Kyung Ko and Chongmu Lee∗ Department of Materials Science and Engineering, Inha University, Incheon 22212, Korea (Received 2 January 2020; revised 16 March 2020; accepted 16 March 2020) This study reports the effects of NiO nanoparticle (NP) size on the sensing performance of NiO NP-decorated SnO2 nanorods (NRs). NiO NP-decorated SnO2 NRs were synthesized using a two-step process: 1) thermal evaporation of tin powders in an oxidizing atmosphere based on the vapor-liquid-solid growth mechanism and 2) solvothermal decoration of SnO2 NRs with NiO NPs. X-ray diffraction and transmission electron microscopy analyses revealed that both the SnO2 NRs and the NiO NPs were polycrystalline. Scanning electron microscopy images showed that the diameters of the NRs ranged from 100 to 200 nm and that those of the small and the large NiO NPs ranged from 20 to 30 nm and from 80 to 180 nm, respectively. The small NiO NPdecorated SnO2 NRs showed stronger response to NO2 than did the large NiO NP-decorated SnO2 NRs over the concentration range of 0.5 – 100 ppm. Decoration of SnO2 NRs with small NiO NPs resulted in enhanced sensing performance whereas decoration of SnO2 NRs with large NiO NPs deteriorated the sensing performance. The superior NO2 gas sensing performance of the small NiO NP-decorated SnO2 NR sensor as compared to that of the large NiO NP-decorated SnO2 NR sensor was attributed to a higher ratio of n-SnO2 to p-NiO and a higher number of p-n heterojunctions for the same volume of NiO in the former than in the latter. In addition, the small NiO NP-decorated SnO2 NR sensors showed selectivity toward NO2 against other competing gases such as SO2 , CO2 , CO, H2 , C7 H8 and C6 H6 . Keywords: Gas sensors, NO2 , Nanoparticles, SnO2 , NiO DOI: 10.3938/jkps.77.482
I. INTRODUCTION Semiconducting metal oxides (SMOS) have many merits as gas sensor materials such as low cost, high sensitivity, rapid sensing time, extended reliability, low detection limits, ease of fabrication, simple measurements, long life, and some resistance to poisoning. However, SMOs also have some demerits such as high working temperature and poor selectivity. A range of techniques, such as metal catalyst-doping [1–6], heterostructure formation [7–9], radiation-assisted treatment with energetic particles including ion beams, electrons, and ultraviolet light [10–12], grain size control [13], and morphology control [14,15], have been developed to solve these problems. Of these techniques, heterostructure formation in particular has been intensively studied in recent years. Heterostructures can be formed using many different means including decoration of one type of SMO nanostructures with another kind of SMO nanoparticles, formation of core-shell nanostructures, formation of a simple mixture of two different types of SMO nanoparticles (NPs), and bilayer nanostructures. Of these nanostructures, NP∗ E-mail:
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