Electronic Transitions and the High Pressure Chemistry and Physics of Solids
There is no paucity of books on high pressure. Beginning with P. W. Bridgman's The Physics of High Pressure, books of general interest include the two-volume Physics and Chemistry of High Pressure, edited by R. S. Bradley, and the series, Advances in High
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A. D. Buckingham, University Chemical Laboratory, Cambridge, U.K.
Other titles in the series Advanced Molecular Quantum Mechanics, R. E. Moss Chemical Applications of Molecular Beam Scattering, K. P. Lawley and M. A. D. Fluendy
Electronic Transitions and the High Pressure Chemistry and Physics of Solids
Electronic Transitions and the High Pressure Chemistry and Physics of Solids H. G. DRICKAMER
AND
C. W. FRANK
School of Chemical Sciences and Materials Research Laboratory, University of Illinois, Urbana
CHAPMAN AND HALL· LONDON
First published 1973 by Chapman and Hall Ltd 11 New Fetter Lane, London EC4P 4EE
© 1973 H. G. Drickamer and C. W. Frank Softeover reprint of the hardcover 1st edition 1973 Filmset by Santype Ltd, Salisbury, Wilts. Fletcher & Son Ltd, Norwich, Norfolk
ISBN-13: 978-94-011-6898-4 e-ISBN-13: 978-94-011-6896-0 DOl: 10.1007/978-94-011-6896-0 All rights reserved. No part of this book may be reprinted, or reproduced or utilized in any form or by any electronic, mechanical or other means, now known or hereafter invented, including photocopying and recording, or in any information storage and retrieval system, without permission in writing from the Publisher.
Distributed in the U.S.A. by Halsted Press, a Division of John Wiley & Sons, Inc., New York
Contents
page
ACKNOWLEDGEMENTS
ix
PREFACE
1 Introduction 2 Theories of electronic energy levels
1 In
molecules and
solids 3 Thermal versus optical transitions 4 Phenomenological description of continuous electronic transitions 5 Methods for studying electronic structure at very high pressure 6 Shifts of energy levels with pressure 7 Electronic transitions in metals and insulator-metal transitions 8 Spin changes in iron complexes 9 The reduction of ferric iron 10 Changes of oxidation state and spin state 11 Reactions in aromatic molecules and complexes
vii
viii
6 33 44
60 72 110 126 152 172 185
APPENDIX
210
AUTHOR AND SUBJECT INDEXES
211
Acknowledgements
The authors wish to acknowledge with gratitude permISSIOn to use figures from the following sources: Journal of Chemical Physics, the Physical Review, and Physical Review Letters published by the American Institute of Physics; Proceedings of the National Academy of Sciences published by the Academy; Science published by the American Association for the Advancement of Science; the Journal of Solid State Chemistry published by Academic Press; Journal of Physics and Chemistry of Solids published by Pergamon Press; 'Solid State Physics, Volume 17,' 'The Physics of Solids Under Pressure,' and 'Organic Charge Transfer Complexes' published by Academic Press.
viii
Preface
There is no paucity of books on high pressure. Beginning with P. W. Bridgman's The Physics of High Pressure, books of general interest include the two-volume Physics and Chemistry of High Pressure, edited by R. S. Bradley, and the series, Advances in High Pressure Research, as well as the report on the Lake George Conference in 1960. Solid state physics is well represented by Solids Under Pressure, edited by P
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