Fundamentals of Latex Film Formation Processes and Properties

This book introduces the reader to latex, which is a colloidal dispersion of polymer particles in water, and explains how useful products are made from it. The primary focus is the process by which wet latex can be transformed into coatings, adhesives, an

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Springer Laboratory Manuals in Polymer Science

Editor Prof. Harald Pasch Chair of Polymer Characterization Department of Chemistry and Polymer Science University of Stellenbosch Private Bag X1 7602 Matieland South Africa e-mail: [email protected]

Editorial Board PD Dr. Ingo Alig Deutsches Kunststoff-Institut Abt. Physik Schloßgartenstr. 6 64289 Darmstadt Germany e-mail: [email protected] Prof. Josef Janca Université de La Rochelle Pole Sciences et Technologie Avenue Michel Crépeau 17042 La Rochelle Cedex 01 France e-mail: [email protected] Prof. W.-M. Kulicke Inst. f. Technische u. Makromol. Chemie Universität Hamburg Bundesstr. 45 20146 Hamburg Germany e-mail: [email protected]

For other titles published in this series, go to www.springer.com/series/3721

Prof. Harald Pasch Deutsches Kunststoff-Institut Abt. Analytik Schloßgartenstr. 6 64289 Darmstadt Germany e-mail: [email protected]

Joseph L. Keddie • Alexander F. Routh

Fundamentals of Latex Film Formation Processes and Properties

Joseph L. Keddie Department of Physics & Surrey Materials Institute University of Surrey Guildford UK

Alexander F. Routh Department of Chemical Engineering and Biotechnology & BP Institute University of Cambridge Cambridge UK

Published by Springer, P.O. Box 17, 3300 AA Dordrecht, The Netherlands In association with Canopus Academic Publishing Limited, 15 Nelson Parade, Bedminster, Bristol, BS3 4HY, UK

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ISBN 978-90-481-2844-0 e-ISBN 978-90-481-2845-7 Springer Dordrecht Heidelberg London New York Library of Congress Control Number: 2009940449 © Canopus Academic Publishing Limited 2010 No part of this work may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, microfilming, recording or otherwise, without written permission from the Publisher, with the exception of any material supplied specifically for the purpose of being entered and executed on a computer system, for exclusive use by the purchaser of the work.

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Preface

This book has emerged out of our long-time research interests on the topic of latex film formation. Over the years we have built up a repertoire of slides used in conference presentations, short courses and tutorials on the topic. The story presented in this book has thereby taken shape as it has been told and re-told to a mix of academic and industrial audiences. The book presents a wide body of work accumulated by the polymer colloids community over the past five decades, but the selection of examples has been flavoured by our particular experimental interests and development of mathematical models. We intend the book to be a starting point for academic and industrial scientists beginning research on latex film formation. The emphasis is on fundamental mechanisms, however, and not on applications nor on specific effects of formulations. We hope that the book conso