High-Dielectric-Constant All-Organic/Polymeric Composite Actuator Materials
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High-Dielectric-Constant All-Organic/Polymeric Composite Actuator Materials Cheng Huang,1 Ji Su,2 and Q.M. Zhang1 1
Materials Research Institute and Electrical Engineering Department, The Pennsylvania State University, University Park, PA 16802 2 Advanced Materials and Processing Branch, NASA Langley Research Center, Hampton, VA 23681
ABSTRACT Among various electroactive polymer (EAP) actuator materials developed recently, the class of EAPs whose responses are stimulated by external electrical fields (often known as the field type EAPs) is especially attractive due to their high strain level and elastic energy density. However, for most field type EAPs, dielectric constant is low, generally less than 10. Consequently, these polymers usually require high electric fields (>100 V/µm) to generate high elastic energy density which limits their applications. In this paper, we will investigate some avenues to significantly raise the dielectric constant and electromechanical response in field type polymeric materials. By exploiting an all-organic composite approach in which high-dielectric-constant organic particulates were blended with a polymer matrix, a polymeric-like material can reach a dielectric constant higher than 400, which results in a significant reduction of the applied field to generate high strain with high elastic energy density. An all-polymer high-dielectric-constant (K>1,000 @1 kHz) percolative composite material was fabricated by the combination of conductive polyaniline particles (K>105) within a fluoroterpolymer matrix (K>50). These high-K polymer hybrid materials also exhibit high electromechanical responses under low applied fields. In addition, a three-component all-organic composite was designed and prepared to improve the dielectric constant and the electromechanical response, as well as the stability of the composites, in which a high-dielectric-constant organic dielectric phase and an organic conductive phase were embedded into the soft dielectric elastomer matrix. INTRODUCTION High performance soft electronic materials are key elements in advanced electronic devices for broad range applications including capacitors, actuactors, artificial muscles and organs, smart materials and structures, microelectromechanical (MEMS) and microfluidic devices, acoustic devices and sensors[1-4]. In recent years we have witnessed great progress in the electroactive polymers (EAPs), renowned for their excellent mechanical properties such as flexibility and light weight, which are attractive for a wide range of electromechanical and biomedical applications[1,3-5]. Among various EAPs developed recently, the class of EAPs whose responses are stimulated by external electrical fields (often known as the field type EAPs) is especially attractive due to the fact that their level of strain and elastic energy density are far above those of the traditional piezoelectric materials. However, these polymers usually require high electric fields (>100 V/µm) to generate high elastic energy density which limits their ap
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