High Temperature Polymer Electrolyte Membrane Fuel Cells Approaches,
This book is a comprehensive review of high-temperature polymer electrolyte membrane fuel cells (PEMFCs). PEMFCs are the preferred fuel cells for a variety of applications such as automobiles, cogeneration of heat and power units, emergency power, a
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High Temperature Polymer Electrolyte Membrane Fuel Cells Approaches, Status, and Perspectives
High Temperature Polymer Electrolyte Membrane Fuel Cells
Qingfeng Li • David Aili • Hans Aage Hjuler • Jens Oluf Jensen Editors
High Temperature Polymer Electrolyte Membrane Fuel Cells Approaches, Status, and Perspectives
Editors Qingfeng Li Department of Energy Conversion and Storage Technical University of Denmark Lyngby, Denmark Hans Aage Hjuler Danish Power Systems Kvistga˚rd, Denmark
David Aili Department of Energy Conversion and Storage Technical University of Denmark Lyngby, Denmark Jens Oluf Jensen Department of Energy Conversion and Storage Technical University of Denmark Lyngby, Denmark
ISBN 978-3-319-17081-7 ISBN 978-3-319-17082-4 (eBook) DOI 10.1007/978-3-319-17082-4 Springer Cham Heidelberg New York Dordrecht London Library of Congress Control Number: 2015948948 # Springer International Publishing Switzerland 2016 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. Printed on acid-free paper Springer International Publishing AG Switzerland is part of Springer Science+Business Media (www.springer.com)
Contents
1
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Jens Oluf Jensen, Hans Aage Hjuler, David Aili, and Qingfeng Li
1
2
Modifications of Sulfonic Acid-Based Membranes . . . . . . . . . Antonino S. Arico`, Vincenzo Baglio, Francesco Lufrano, Alessandro Stassi, Irene Gatto, Vincenzo Antonucci, and Luca Merlo
5
3
Acid–Base Chemistry and Proton Conductivity . . . . . . . . . . . Qingfeng Li, David Aili, Robert F. Savinell, and Jens Oluf Jensen
37
4
Applications of Acid–Base Blend Concepts to Intermediate Temperature Membranes . . . . . . . . . . . . . . . Jochen Kerres
59
5
Pyridine Containing Aromatic Polyether Membranes . . . . . . Joannis K. Kallitsis, Aikaterini K. Andreopoulou, Maria Daletou, and Stylianos Neophytides
91
6
Techniques for PBI Membrane Characterization . . . . . . . . . 127 Dirk Henkensmeier a