Hydrogen in Metals I Basic Properties
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Basic Properties Edited by G. Alefeld and J. V/51kl With Contributions by G. Alefeld R.M. Cotts K.W. Kehr H. Kronmtiller H. Peisl A. Seeger K. Sk61d T. Springer A. C. Switendick J. V61kl F.E. Wagner H. Wagner W. E. Wallace G. Wortmann
With 178 Figures
Springer-Verlag Berlin Heidelberg New York 1978
Professor Dr. Georg Alefeld Dr. Johann V61kl P h y s i k - D e p a r t m e n t der T e c h n i s c h e n Universit~it M i i n c h e n , D - 8 0 4 6 G a r c h i n g , Fed. Rep. o f G e r m a n y
ISBN 3-540-08705-2 Springer-Verlag Berlin Heidelberg New York ISBN 0-387-08705-2 Springer-Verlag New York Heidelberg Berlin
Library of Congress Cataloging in Publication Data. Main entry under title: Hydrogen in metals. (Topics in applied physics; v. 28-29). Includes bibliographical references and indexes. Contents: v. 1. Basic properties. v. 2. Application-oriented properties. 1. Metals-Hydrogen content. 1. Alefeld,G., 1933 , I1. V61kl, J., 1936--, TH690.H97 669'.94 78-4487. This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks. Under § 54 of the German Copyright Law, where copies are made for other than private use, a fee is payable to the publisher, the amount of the fee to be determined by agreement with the publisher. © by Springer-Verlag Berlin Heidelberg 1978 Printed in Germany The use of registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Monophoto typesetting, offset printing and bookbinding: Bri~hlsche Universit~itsdruckerei, Lahn-Giel?,en 2153/3130-543210
Preface
Progress in solid-state sciences results from many effects:the preparation of new materials, the development of new experimental methods, or increase in technological interest. All three aspects are valid for research on hydrogen in metals. Although these systems are not completely new, advanced preparation techniques yielding well-defined samples not only made the results on diffusion, solubility, and phase transitions for example, more and more reproducible, but also stimulated the application of new methods like neutron scattering and MSssbauer effect. The technological interests range from old problems like hydrogen embrittlement to applications of metal-hydrogen systems in fission and fusion reactors, fuel cells, as energy storage systems, etc. The concept for future energy transport and supply known as "hydrogen economy" also caused appreciable increase in research on interaction of hydrogen with metals. Due to this broad interest, this group of materials presently is studied by many scientists affiliated with various disciplines such as physics, chemistry, physical chemistry, metallurgy and engineering. Therefore, research results are scattered
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