Hyperfine Interactions
In Chapter 2 we have, for the sake of simplicity, dealt with transitions between unperturbed energy levels of “bare” nuclei and have called the mean transition energy E0. In reality, however, we deal with atoms and molecules, with gases, liquids, and soli
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Editors Margot Becke Michael F. Lappert John L. Margrave Robert W. Parry
Christian K. J ~rgensen Stephen J. Lippard Kurt Niedenzu Hideo Yamatera
Philipp Gtitlich Rainer Link Alfred Trautwein
Mossbauer Spectroscopy and Transition Metal Chemistry With 160 Figures
Springer-Verlag Berlin Heidelberg GmbH 1978
Prof. Dr. Philipp Glitlich Dr. rer. nat. Rainer Link Johannes Gutenberg-Universitat Institut fUr Anorganische und Analytische Chemie J).6500 Mainz
Prof. Dr. Alfred X. Trautwein Fachbereich "Angewandte Physik" der Universitat des Saarlandes 0-6600 Saarbriicken 11
ISBN 978-3-662-12547-2 ISBN 978-3-662-12545-8 (eBook) DOI 10.1007/978-3-662-12545-8 Library of Congress Cataloging in Publication Data. Giitlich, Philipp, 1934Mossbauer spectroscopy and transition metal chemistry. (Inorganic chemistry concepts; v. 3) Bibliography: p. Includes index. 1. Transition metals-Spectra. 2. Mossbauer spectroscopy. I. Link, Rainer, 1943- joint author. II. Trautwein, Alfred, 1940- joint author. III. Title. IV. Series. QC462.T86G83 546'.6 78-2364 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks. Under § 54 of the German Copyright Law where copies are made for other than private use, a fee is payable to the publisher, the amount of the fee to be determined by agreement with the publisher. © by Springer-Verlag Berlin Heidelberg 1978 Originally published by Springer-Verlag Berlin Heidelberg New York in 1978 Sof'tcover reprint of the hardcover I st edition 1978
The use of registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesettin~: Elsner & Behrens, Oftersheim. 2152/3140-543210
Preface
Two decades have passed since the original discovery of recoilless nuclear gamma resonance by Rudolf Mossbauer; the spectroscopic method based on this resonance effect - referred to as Mossbauer spectroscopy - has developed into a powerful tool in solid-state research. The users are chemists, physicists, biologists, geologists, and scientists from other disciplines, and the spectrum of problems amenable to this method has become extraordinarily broad. In the present volume we have confined ourselves to applications of Mossbauer spectroscopy to the area of transition elements. We hope that the book will be useful not only to non-Mossbauer specialists with problem-Oriented activities in the chemistry and physics of transition elements, but also to those actively working in the field of Mossbauer spectroscopy on systems (compounds as well as alloys) of transition elements. The first five chapters are directed to introducing the reader who is not familiar with the technique to the principles of the recoilless nuclear resonance effect, the hyp
