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ORIGINAL PAPER

Influence of MWCNTs and nano-Fe3O4 on the properties and structure of MWCNTs/ Fe3O4/PLA composite film with electromagnetic interference shielding function Shuqiang Liu 1,2 & Peng Wang 2 & Yaru Yang 3 & Yong Yang 1 & Gaihong Wu 2 & Huimin Li 2 & Kaiwen Wang 2 & Bowen Wang 2 & Mingfang Liu 2 & Yao Zhang 2 & Jie Wu 2 & Jie Zhang 2 & Yifan Jing 2 & Fu Li 2 & Man Zhang 2 Received: 13 February 2020 / Accepted: 26 May 2020 # The Polymer Society, Taipei 2020

Abstract A large number of electronic devices could generate a lot of electromagnetic waves, which could interfere with other equipment and harm the human body. Therefore, an electromagnetic interference shielding (EMI) material is urgently needed to protect the human body and the electronic equipment. In this paper, the multi-wall carbon nanotubes (MWCNTs) and the nano-Fe3O4 were added into the polylactic acid (PLA) matrix to form the composite film with electromagnetic interference shielding performance. And the structure and properties of MWCNTs/Fe3O4/PLA composite films, such as the morphology, chemical structure, crystallization, mechanical property, conductive property, magnetic property and electromagnetic interference shielding property, were researched. The result shows that too much Fe3O4 could lead to agglomeration, and the coupling agent KH570 had grafted and modified the surface of MWCNTs. The MWCNTs and nano-Fe3O4 could increase the crystallinity of PLA matrix. With the increase of MWCNTs, the maximum tensile stress of composite films gradually increased, and the maximum tensile strain decreased, and the resistance value showed a significant downward trend. The Fe3O4 could improve the magnetic properties of composite film. The MWCNTs and Fe3O4 could improve the electromagnetic interference shielding efficiency (EMI SE). The MWCNTs played a more significant role than the Fe3O4 in the process of EMI, and the EMI SE of the composite film with 3:1 ratios of MWCNTs/Fe3O4 could rise to 22 dB. Keywords Multi-walled carbon nanotubes . Nano-Fe3O4 . Polylactic acid . Electromagnetic interference shielding . Composite film

Introduction

Shuqiang Liu and Peng Wang contributed equally to this work and should be considered co-first authors. * Shuqiang Liu [email protected] * Gaihong Wu [email protected] 1

Jiangsu R&D Center of the Ecological Textile Engineering & Technology, Yancheng Polytechnic College, Yancheng 224005, China

2

College of Textile Engineering, Taiyuan University of Technology, Taiyuan 030024, China

3

College of Materials and Textile Engineering, Jiaxing University, Jiaxing 314001, Zhejiang, China

With the development of electronic information technology, a large number of electronic devices already extended to people’s daily life. These electronic devices had made our life more and more convenient and our work more and more efficient, but also brought many problems. For example, these electronic devices could generate a lot of electromagnetic waves, which would affect and interfere with the sensitivity and precision of o