IR spectroscopic and photoluminescence studies of plasma polymerized organic thin films based on tea tree oil
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IR spectroscopic and photoluminescence studies of plasma polymerized organic thin films based on tea tree oil Beena Mol1 · Jemy James2 · Cyriac Joseph2 · M. R. Anantharaman1 · M. Junaid Bushiri1 Received: 29 November 2019 / Accepted: 26 March 2020 © Springer Nature Switzerland AG 2020
Abstract Plasma-assisted synthesis of transparent, environment friendly, lightweight, flexible and stable organic thin films from naturally occurring precursors were emerging as potential candidates for organic semiconductor industry. In the present study, tea tree (Malaleuca alternifolia) oil based polymer thin films were deposited on glass and silicon substrate by using radio frequency plasma polymerization technique. The polymer thin films were characterized with atomic force microscopy (AFM) and Fourier transform infrared (FTIR) spectroscopy techniques. AFM images indicate the formation of homogenous film on the substrate surface. FTIR spectra gives bands related to methyl and methylene groups which confirms the formation of chain branching in the polymer films. Relatively intense infrared (IR) bands obtained from films deposited on glass substrate reveals that glass substrate is more favourable for the growth of polymers than silicon substrate. Optical band gap of the polymerized thin film on glass substrate was estimated using Tauc plot which gives a value of 3.19 eV, indicating the semiconducting nature of the material. Photoluminescence (PL) emission in the yellow region were observed from both the samples and its CIE colour coordinates also matches with yellow emission. Broad visible emission observed in the wavelength range 465–695 nm indicates the presence of multichromophores in the polymer film. Samples also gives IR emission in the wavelength range of 850–1090 nm, upon excitation with a wavelength of 785 nm contributed to polaronic transitions. Keywords Rf plasma polymerization · Tea tree oil · Thin film · Photoluminescence · Infrared emission
1 Introduction Polymer based thin films are important materials for the fabrication of next generation flexible electronic devices [1], sensors [2], organic light emitting devices [3], organic field effect transistors [4] and organic photovoltaic devices [5] as insulating, conducting or semiconducting layers in electronic devices [1, 6-7]. Modification of polymer structure with functional groups and organic moieties changes its physical and chemical properties which consequently provides better optical and electronic responses [8]. Recently, researchers attention is focussed on the development of low cost electronic grade eco-friendly, natural
oil based polymer films for flexible electronic devices [9]. But the development of natural oil based polymers for flexible electronic components is a challenging task because natural oil contains several organic functional moieties. Neverthless, organic polymer thin films can be deposited on different substrates by using methods such as spin coating [10], dip coating [11], evaporation [12] and solvent casting [13]. Radio frequency (rf )
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