Local Dielectric Relaxation by Solvation Dynamics
This chapter is concerned with a method of measuring dielectric relaxation phenomena locally, in order to complement the information regarding the dynamics of molecules inferred from the various macroscopic dielectric techniques outlined in previous chapt
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Springer-Verlag Berlin Heidelberg GmbH
F. Kremer · A. Schönhals (Eds.)
Broadband Dielectric Spectroscopy With 393 Figures and 22 Tables
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Professor Dr. Friedrich Kremer University of Leipzig Faculty of Physics and Geosciences Linnéstraße 5 04103 Leipzig, Germany e-mail: [email protected]
Priv.-Doz. Dr. Andreas Schönhals Federal Institute for Materials Research and Testing Unter den Eichen 87 12205 Berlin, Germany e-mail: [email protected]
Library of Congress Cataloging-in-Publication Data Broadband dielectric spectroscopy / F. Kremer, A. Schönhals (eds.) p. cm Includes bibliographical references and index. ISBN 978-3-642-62809-2 ISBN 978-3-642-56120-7 (eBook) DOI 10.1007/978-3-642-56120-7 1. Broadband dielectric spectroscopy. I. Kremer, F. (Friedrich), 1949-II. Schönhals, A. (Andreas) ¢ QC454.B74 B76 2002 535.8 4–dc21 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable for prosecution under the German Copyright Law.
http://www.springer.de © Springer-Verlag Berlin Heidelberg 2003 Originally published by Springer-Verlag Berlin Heidelberg New York in 2003
Softcover reprint of the hardcover 1st edition 2003 The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Product liability: The publisher cannot guarantee the accuracy of any information about dosage and application contained in this book. In every individual case the user must check such information by consulting the relevant literature. Coverdesign: Erich Kirchner, Heidelberg Figure within the cover modified from: P. Lunkenheimer, U. Schneider, R. Brand and A. Loidl, Physikalische Blätter 56, 35 (2000) U. Schneider, R. Brand, P. Lunkenheimer and A. Loidl, Phys. Rev. Lett. 84, 5560 (2000) Typesetting: Fotosatz-Service Köhler GmbH, Würzburg SPIN: 10719499
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Foreword
The interaction of electromagnetic (EM) radiation with molecular systems gives rise to quantized transitions between the electronic, vibrational and rotational molecular energy states which may be observed by UV/visible and infra-red absorption spectroscopies at frequencies above about 1 THz (1012 Hz). These quantum spectroscopies for molecules in the gaseous, liquid and solid states form a large part of physical chemistry and chemical physics. However, if one asks a fellow scientist “what happens when EM radiation in the range 10–6
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