Microporous Organic Polymers for Carbon Dioxide Capture
Microporous organic polymers (MOPs) are a unique class of porous materials consisting solely of the light elements (C, H, O, N, etc.). A series of vivid characteristics of MOPs, such as high-specific surface area, good physicochemical stability, diverse p
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Microporous Organic Polymers for Carbon Dioxide Capture Yali Luo and Bien Tan
Abstract Microporous organic polymers (MOPs) are a unique class of porous materials consisting solely of the light elements (C, H, O, N, etc.). A series of vivid characteristics of MOPs, such as high-specific surface area, good physicochemical stability, diverse pore dimensions, topologies, and chemical functionalities, make them suitable adsorbents for CO2 capture. In this chapter, MOPs are categorized into four classes according to the types of organic reactions and the chemical structures of the resulting materials: hypercrosslinked polymers (HCPs), covalent organic frameworks (COFs), polymers of intrinsic microporosity (PIMs), and conjugated microporous polymers (CMPs). For each type of the polymer network, the state-of-the-art development in the design, synthesis, characterization, and the CO2 sorption performance is reviewed. Strategies for controlling CO2 uptake capacity and adsorption enthalpy via manipulation of surface area, pore size, and functionality are discussed in detail. These studies would open up many new possibilities for the development of the novel solid sorbents targeting the CO2 capture process. It is expected that this chapter will not only summarize the main research activities in this field, but also find possible links between basic studies and practical applications.
Abbreviations ACMP Acetylene gas mediated conjugated microporous polymers BA Benzyl alcohol BC Benzyl chloride BCMA 9,10-Bis(chloromethyl)anthracene
Y. Luo · B. Tan (*) Department of Chemistry, Huazhong University of Science and Technology, Wuhan, People’s Republic of China e-mail: [email protected]
A.-H. Lu and S. Dai (eds.), Porous Materials for Carbon Dioxide Capture, Green Chemistry and Sustainable Technology, DOI: 10.1007/978-3-642-54646-4_5, © Springer-Verlag Berlin Heidelberg 2014
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BCMBP 4,4-Bis(chloromethyl)-1,1-biphenyl BDM 1,4-Benzenedimethanol BET Brunauer–Emmett–Teller BILPs Porous benzimidazole-linked polymers (±)BINAM (±)-2,2′-Diamino-1,10-binaphthalene BINOL Binaphthol CCS Carbon capture and storage CMPs Conjugated microporous polymers COFs Covalent organic frameworks CPOP Carbazole-based porous organic polymer DCX Dichloroxylene DVB Divinylbenzene FDA Formaldehyde dimethyl acetal GCMC Grand canonical Monte Carlo HATP 2,3,6,7,10,11-Hexaaminotriphenylene HCPs Hypercrosslinked polymers MOFs Metal organic frameworks MOPs Microporous organic polymers PAE Poly(aryleneethynylene) PAFs Porous aromatic frameworks PBI Poly(benzimidazole) PIMs Polymers of intrinsic microporosity PMDA Pyromellitic acid dianhydride PPNs Porous polymer networks Py Pyrrole Qst Isosteric heat of CO2 adsorption St Styrene TFPM Tetrakis(4-formylphenyl)methane TPI Triazine-based porous polyimide TpPa-1 1,3,5-Triformylphloroglucinol with p-phenylenediamine TpPa-2 1,3,5-Triformylphloroglucinol with 2,5-dimethyl-p-phenylenediamine TZPIMs MOPs functionalized with CO2-philic pendant tetrazole
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