Pr-Yb (Praseodymium-Ytterbium)
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Section III: Supplemental Literature Review
Pr-Yb (Praseodymium-Ytterbium) H. Okamoto
Reference
The Pr-Yb phase diagram was unknown in [Massalski2]. A schematic Pr-Yb phase diagram shown in Fig. 1 was proposed by [1999Gio] by assuming close similarity of this system to the Nd-Yb system. Pr-Yb crystal structure data are shown in Table 1.
Table 1
1999Gio: M. Giovannini, A. Saccone, and R. Ferro, The Isothermal Section at 450C of the Yb-Pr-Mg System, Intermetallics, 1999, 7, p 909-916
Pr-Yb crystal structure data
Phase
Composition, at.% Yb
Pearson symbol
Space group
Strukturbericht designation
Prototype
(bPr) (aPr) (cYb) (bYb)
0-? 0-? ?-100 ?-100
cI2 hP4 cI2 cF4
Im3m P63/mmc Im3m Fm3m
A2 A3¢ A2 A1
W aLa W Cu
Weight Percent Ytterbium 0
10
20
30
50
40
60
70
80
90
100
1400
L1
L2
1200
L1 + L2
Temperature, °C
1000 931°C
(βPr)
800 795°C
819°C 795°C
(γYb) (αPr)
600
(βYb) 400
200
0
0
Pr
10
20
30
40
50
60
70
80
90
Atomic Percent Ytterbium
Fig. 1 Pr-Yb phase diagram
386
Journal of Phase Equilibria and Diffusion Vol. 29 No. 4 2008
100
Yb
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