The history of organoplatinum chemistry in Iran: 40-year research
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REVIEW
The history of organoplatinum chemistry in Iran: 40‑year research Reza Babadi Aghakhanpour1 · Sareh Paziresh1 · S. Masoud Nabavizadeh1 · S. Jafar Hoseini1 · Fatemeh Niroomand Hosseini2 Received: 23 December 2019 / Accepted: 24 February 2020 © Iranian Chemical Society 2020
Abstract This review article is based on the scientific investigations of Prof. Mehdi Rashidi during his working years in Shiraz University, Chemistry Department, Organometallic Chemistry Laboratory. Herein, we tried to overlook 40 years of his researches and intend to briefly point out all his publications during his research years. Prof. Rashidi’s researches were mostly focused on the synthesis and characterization of organoplatinum(II) and (IV) complexes having different applications. In this regard, he introduced many synthetic methods for new organoplatinum complexes mostly with the help of NMR spectroscopy and X-ray crystallography as characterization techniques. His researches were divided into some main themes like “substitution reactions,” “oxidative addition reactions,” “biological properties” and “photophysical properties” in organoplatinum chemistry. In this review article, the mentioned outlined items are briefly discussed as different areas of research that most of the contents are the outcomes of many Ph.D. and master theses. Besides, all the publications he authored are fully cited in the present review article. Keywords Organoplatinum chemistry · Substitution reactions · Oxidative addition reactions · Biological properties · Photophysical properties Abbreviations ppy 2-Phenylpyridinate bzq Benzo[h]quinolinate tpy 2-(p-Tolyl)pyridinate FDA Food and drug administration HOR Hydrogen oxidation reaction EOR Ethanol oxidation reaction MOR Methanol oxidation reaction ORR Oxygen reduction reaction MLCT Metal-to-ligand charge transfer ILCT Intraligand charge transfer LC Ligand-centered COD Cycloocta-1,5-diene bpy 2,2′-Bipyridine phen 1,10-Phentantroline dppm 1,1-Bis(diphenylphosphino)methane * S. Masoud Nabavizadeh [email protected] 1
Rashidi Laboratory of Organometallic Chemistry, Department of Chemistry, College of Sciences, Shiraz University, 71467‑13565 Shiraz, Iran
Department of Chemistry, Shiraz Branch, Islamic Azad University, 71993–37635 Shiraz, Iran
2
dppe 1,2-Bis(diphenylphosphino)ethane dppa N,N-Bis(diphenylphosphino)amine dppf 1,1′-Bis(diphenylphosphino)ferrocene dfppe 1,2-Bis(bis(pentafluorophenyl)phosphine)ethane KIE Kinetics isotope effect SDS Sodium dodecyl sulfate DFT Density functional theory phpz 1-Phenylpyrazolate NMR Nuclear magnetic resonance BSA Bovine serum albumin HSA Human serum albumin PTA 1,3,5-Triaza-7-phosphaadamantane EtB Ethidium bromides CD Circular dichroism CVD Chemical vapor deposition PVP Polyvinylpyrrolidone TEM Transmission electron microscope SAED Selected area electron diffraction RGO Reduced graphene oxide XRD X-ray diffraction dppp 1,3-Bis(diphenylphosphino)propane HOMO Highest occupied molecular orbital LUMO Lowest unoccupied mole
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