Quantitative Infrared Spectroscopy for Understanding of a Condensed Matter

This book is intended to provide a course of infrared spectroscopy for quantitative analysis, covering both bulk matter and surface/interface analyses. Although the technology of Fourier transform infrared (FT-IR) spectroscopy was established many years a

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Quantitative Infrared Spectroscopy for Understanding of a Condensed Matter

Quantitative Infrared Spectroscopy for Understanding of a Condensed Matter

Takeshi Hasegawa

Quantitative Infrared Spectroscopy for Understanding of a Condensed Matter

123

Takeshi Hasegawa ICR Kyoto University Uji, Kyoto Japan

ISBN 978-4-431-56491-1 DOI 10.1007/978-4-431-56493-5

ISBN 978-4-431-56493-5

(eBook)

Library of Congress Control Number: 2017935560 © Springer Japan KK 2017 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Printed on acid-free paper This Springer imprint is published by Springer Nature The registered company is Springer Japan KK The registered company address is: Chiyoda First Bldg. East, 3-8-1 Nishi-Kanda, Chiyoda-ku, Tokyo 101-0065, Japan

Preface

Infrared (IR) spectroscopy strongly attracted the attention of theoretical physicists from the 1930s until the 1970s, and most of the important fundamentals were comprehensively organized in terms of molecular vibrations and rotations along with the rapid progress of quantum mechanics and chemistry. For experimental chemists, commercial IR spectrometers played a great role in the latter half of the twentieth century, and theoretical fundamentals were confirmed quantitatively by using a spectrometer. For example, the theoretical prediction of the Fermi resonance was experimentally recognized for many organic compounds. At this early stage of IR spectroscopy, theoretical and experimental chemists made great efforts to establish fundamentals for analyzing IR spectra for chemistry. Some textbooks were devoted to summarizing IR bands characteristic of chemical groups in many organic and inorganic compounds in various chemical environments involving solvents and temperature. Correlations of some IR bands to hydrogen bonding, molecular conformation, and crystallinity were also studied, and IR spectroscopy was thus recogn