Spatial and temporal variability in discharge and nitrate in Iowa subsurface drains

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Spatial and temporal variability in discharge and nitrate in Iowa subsurface drains Richard H. Coupe & Jonathon D. Thornburg & Erik A. Smith & Paul D. Capel

Received: 5 April 2020 / Accepted: 24 September 2020 # This is a U.S. government work and not under copyright protection in the U.S.; foreign copyright protection may apply 2020

Abstract Agricultural subsurface drainage can be an important conduit of nitrate from agricultural fields to streams. This study focused on understanding the variability in nitrate concentrations and loads, exported by subsurface drains, into a small, north-central Iowa stream. Ninety-three subsurface drains in this watershed were sampled up to 5 times between 2006 and 2008. Additionally, 2 subsurface drains and the stream Richard H. Coupe is a retired officer of the U.S. Geological Survey. Electronic supplementary material The online version of this article (https://doi.org/10.1007/s10661-020-08636-0) contains supplementary material, which is available to authorized users. R. H. Coupe Pearl, USA J. D. Thornburg Water Resources Sciences, University of Minnesota, 1985 Buford Ave, St. Paul, MN 55108, USA E. A. Smith U.S. Geological Survey, 1451 Green Rd, Ann Arbor, MI 48105, USA P. D. Capel (*) Department of Civil, Environmental, and Geo-Engineering, University of Minnesota, 500 Pillsbury Drive S.E, Minneapolis, MN 55455, USA e-mail: [email protected]

draining the study area (South Fork Iowa River near Blairsburg, IA, USA) were sampled frequently during the growing seasons in 2007 and 2008. Spatial variability analysis revealed no distinct spatial pattern in nitrate concentrations. The median nitrate concentrations were not significantly different when the drain outlets were characterized by diameter (17–23 cm, 27–48 cm, 60– 108 cm). The eight large subsurface drains (part of the public drainage network) had less variability in nitrate concentration than the smaller drain sizes and generally contributed 70–87% of the total water and nitrate loads exported by subsurface drains to the stream. During high-discharge events, the medium-sized (27–48 cm) subsurface drains discharging to the stream became more important by contributing a higher discharge and nitrate load. The temporal variability examined in this study found that discharge and nitrate loads were influenced by the amount of precipitation that had occurred over the previous months. This paper demonstrates the spatial and within-season homogeneity of nitrate delivery to a stream from an intensely agricultural landscape that has subsurface drainage. Keywords Artificial subsurface drainage . Water quality . Nitrogen . Nitrate

Introduction Present Address: J. D. Thornburg North Central River Forecast Center, NOAA, National Weather Service, 1733 Lake Drive West, Chanhassen, MN 55317, USA

There are many sources of nitrogen in agricultural soil, including, but not limited to, the application of chemical fertilizers, applications of manure, atmospheric

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deposition, and the mineralization of soil organic matter. Howe