Synthesis and Characterization of Poly(limonene) by Photoinduced Controlled Radical Polymerization

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ORIGINAL PAPER

Synthesis and Characterization of Poly(limonene) by Photoinduced Controlled Radical Polymerization Edison Rogério Marques de Oliveira1 · Roniérik Pioli Vieira1 

© Springer Science+Business Media, LLC, part of Springer Nature 2020

Abstract  Limonene is the major component of the essential oil from orange peel, with potential for polymeric production. However, due to some monomer’s structural characteristics its polymerization has low yield, needing new approaches to make the process more attractive. In this paper, limonene photochemical radical polymerization at low temperature was first studied using a combination of type II photo initiators and alkyl halide initiators. Low dispersity polymers (Ð