Thermal Analysis Volume 3: Organic and Macromolecular Chemistry, Cer

Earlier efforts in the field of thermal analysis were concerned with the demonstration of the applicability of techniques to a broad spectrum of materials and to establish the relationship of such techniques with other more accepted method. While such eff

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Volume 3 Organic and Macromolecular Chemistry Ceramics Earth Sciences

Proceedings of the Third International Conference on Thermal Analysis Held at Convention Hall Davos, Switzerland August 23-28, 1971

Volume 1 Advances in Instrumentation Volume 2 Inorganic Chemistry Volume 3 Organic and Macromolecular Chemistry Ceramics Earth Sciences

THERMAL ANALYSIS

Volume 3

Organic and Macromolecular Chemistry H. G. Elias Ceramics G. Bayer Earth Sciences M. Miiller-Vonmoos

Edited by

H. G. Wiedemann Mettler Instrumente AG Greifensee-Ziirich Switzerland

1972 Springer Basel AG

All rights reserved No part of this book may be reproduced in any form, by photostat, microfilm, retrieval system, or any other means, without written permission from the publishers. © Springer Basel AG 1972 Originally published by Birkhauser Verlag Basel in 1972 Softcover reprint of the hardcover 1st edition 1972 ISBN 978-3-0348-5777-2 ISBN 978-3-0348-5775-8 (eBook) DOI 10.1007/978-3-0348-5775-8

v

CONTENTS

Foreword . . . . Preface . . . . . List of Chairmen.

XI XIII XV

Section 3: Organic and Macromolecular Chemistry Survey of Multiple Mechanical Transitions in Polymers in Relation to Thermal Transitions (Plenary Lecture) . . . . R.F. Boyer La preparation et quelques proprietes thermiques des mono- et dihalogenures de l'Hydrazine . . . . . . . . . . . . . . . M. Milojevic et J. Slivnik Thermal Analysis of Aminobenzimidazoles . . . . . . . . . . . . P. Kralik, R. Kada and A. Jurasek Thermal Behaviour of Some Organic Compounds with Ionic Character T. Meisel and Z. Halmos Radiothermogravimetry, a Technique for Determining Pyrolysis Mechanisms . . . . . . . . . . . . . . . . . . . . . . R.H. "Newman, D.F. Glenn, R. W. Jenkins, Jr. and G.E. Lester The Selection of Catalysts by Thermogravimetry. . . . . . . . J, Scheve and K. Heise Investigation of the Melting Behaviour of Organic Substances by Differential Scanning Calorimetry . . . . . . . . . . . . . . E. Marti, O. Heiber, W. Huber, G. Tonn Identification par analyse thermique differentielle et par thermogravimetrie d'une serie d'amino-acides aliphatiques satures H. Harmelin, C. Duval et N. DatXuong Characterization of Unusual Lipids by Novel Thermoanalytical Techniques ...................... A. Seher, F. Spener and H.K. Mangold Pressure Dependence of Phase Transitions in Bis(4'-n-Alkoxybenzal)1,4-Phenylenediamines . . . . . . . . . . . . . . . . . P.D. Garn and R.J. Richardson Acid-Soap Formation in Various Anhydrous Sodium Soaps. H. W. Brouwer and H. L. Spier The Evaluation of Thermosetting Polymers by Thermal Analytical Methods. . . . . . . . . . . . . . . . . . . . . . . W. Manz and J.P. Creedon

3 19 31 43 57 71 83 97 109 123 131 145

VI

CONTENTS

Torsional Braid Analysis of the Cure of a Cycloliphatic Epoxy Resin D. J. Haskins and K. A. Hodd Analysis of the Curing Reactions of Thermosetting Polymers by DSC A. R. Westwood Application of Thermal Analysis to Evaluation of Semiconductor Encapsulation . . . . . . . . . . . . . . . . . . . . K. Ritchie, W.L. Hunter and C. Malkiewicz Studies