Unimolecular and Supramolecular Electronics II Chemistry and Physics

G. C. Solomon C. Herrmann M. A. Ratner Molecular Electronic Junction Transport: Some Pathways and Some IdeasR. M. Metzger D. L. Mattern Unimolecular Electronic DevicesB. Branchi F. C. Simeone M. A. Rampi Active and Non-Active Large-Area Metal–Molecules–Me

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Topics in Current Chemistry

Editorial Board: K.N. Houk C.A. Hunter M.J. Krische J.-M. Lehn S.V. Ley M. Olivucci J. Thiem M. Venturi P. Vogel C.-H. Wong H. Wong H. Yamamoto l

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Topics in Current Chemistry Recently Published and Forthcoming Volumes

Unimolecular and Supramolecular Electronics II Volume Editor: Robert M. Metzger Vol. 313, 2012 Unimolecular and Supramolecular Electronics I Volume Editor: Robert M. Metzger Vol. 312, 2012 Bismuth-Mediated Organic Reactions Volume Editor: Thierry Ollevier Vol. 311, 2012 Peptide-Based Materials Volume Editor: Timothy Deming Vol. 310, 2012 Alkaloid Synthesis Volume Editor: Hans-Joachim Kno¨lker Vol. 309, 2012 Fluorous Chemistry Volume Editor: Istva´n T. Horva´th Vol. 308, 2012 Multiscale Molecular Methods in Applied Chemistry Volume Editors: Barbara Kirchner, Jadran Vrabec Vol. 307, 2012 Solid State NMR Volume Editor: Jerry C. C. Chan Vol. 306, 2012 Prion Proteins Volume Editor: Jo¨rg Tatzelt Vol. 305, 2011 Microfluidics: Technologies and Applications Volume Editor: Bingcheng Lin Vol. 304, 2011

Photocatalysis Volume Editor: Carlo Alberto Bignozzi Vol. 303, 2011 Computational Mechanisms of Au and Pt Catalyzed Reactions Volume Editors: Elena Soriano, Jose´ Marco-Contelles Vol. 302, 2011 Reactivity Tuning in Oligosaccharide Assembly Volume Editors: Bert Fraser-Reid, J. Cristo´bal Lo´pez Vol. 301, 2011 Luminescence Applied in Sensor Science Volume Editors: Luca Prodi, Marco Montalti, Nelsi Zaccheroni Vol. 300, 2011 Chemistry of Opioids Volume Editor: Hiroshi Nagase Vol. 299, 2011 Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures Volume Editors: Ron Naaman, David N. Beratan, David H. Waldeck Vol. 298, 2011 Natural Products via Enzymatic Reactions Volume Editor: Jo¨rn Piel Vol. 297, 2010 Nucleic Acid Transfection Volume Editors: Wolfgang Bielke, Christoph Erbacher Vol. 296, 2010 Carbohydrates in Sustainable Development II Volume Editors: Ame´lia P. Rauter, Pierre Vogel, Yves Queneau Vol. 295, 2010

Unimolecular and Supramolecular Electronics II Chemistry and Physics Meet at Metal-Molecule Interfaces Volume Editor: Robert M. Metzger

With Contributions by B. Branchi  C. Herrmann  K.W. Hipps  M. Hliwa  C. Joachim  C. Li  D.L. Mattern  R.M. Metzger  A. Mishchenko  M.A. Rampi  M.A. Ratner  N. Renaud  F.C. Simeone  G.C. Solomon  T. Wandlowski

Editor Prof. Robert M. Metzger Department of Chemistry The University of Alabama Room 1088B, Shelby Hall Tuscaloosa, AL 35487-0336 USA [email protected]

ISSN 0340-1022 e-ISSN 1436-5049 ISBN 978-3-642-27397-1 e-ISBN 978-3-642-27398-8 DOI 10.1007/978-3-642-27398-8 Springer Heidelberg Dordrecht London New York Library of Congress Control Number: 2011944817 # Springer-Verlag Berlin Heidelberg 2012 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in