Advances in Corrosion Science and Technology Volume 6

This series was organized to provide a forum for review papers in the area of corrosion. The aim of these reviews is to bring certain areas of corrosion science and technology into a sharp focus. The volumes of this series are published approximately on a

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CORROSION SCIENCE AND TECHNOLOGY VOLUME 6

ADVANCES IN CORROSION SCIENCE AND TECHNOLOGY Editors: M. G. Fontana and R. W. Staehle Fontana Corrosion Center, Department of Metallurgical Engineering The Ohio State University, Columbus, Ohio Editorial Board: VITTORIO CARASSITI Universita di Ferrara Ferrara, Italy

JEROME KRUGER National Bureau of Standards Washington, D.C.

MORRIS COHEN National Resean:h Council Ottawa, Ontario, Canada

PAUL LACOMBE Universite Paris-Sud Centre D'Orsay Orsay, France

JOSEPH E. CRALEY Argonne National Laboratory Argonne, Illinois

MARCEL POURBAIX CEBELCOR Brussels, Belgium

T.P. HOAR University of Cambridge Cambridge, England

SAKAE TAJIMA Tokyo City University Tokyo, Japan

A Continuation Order Plan is available for this series. A continuation order will bring delivery of each new volume Immediately upon publication. Volumes are billed only upon actual shipment. For further information please contact the publisher.

ADVANCES IN

CORROSION SCIENCE AND TECHNOL06Y VOLUME 6 Edited by Mars 6. Fontana and Roger W. Staehle

PLE'U. PRESS· 'EW YORK AND LO'DOII

The Library of Congress cataloged the first volume of this title as follows: Advances in corrosion science and technology. v. 1New York, Plenum Press, 1970v. iIIus. 24 cm. Editors: v. 1- M. G. Fontana and R. W. Staehle. 1. Corrosion and anti-corrosives-Collected works. I. Fontana, Marselio Guido, 1910ed. II. Staehle, A. W., 1934ed. TA41S.74.A3 620.1'1223 76-107531

Library of Congress Catalog Card Number 76-107531 ISBN 978-1-4684-8988-0 ISBN 978-1-4684-8986-6 (eBook) DOI 10.1007/978-1-4684-8986-6

©1976 Plenum Press, New York Softcover reprint ofthe hardcover 1st edition 1976 A Division of Plenum Publishing Corporation 227 West 17th Street, New York, N.Y. 10011 All rights reserved No part of this book may be reproduced,stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, microfilming, recording, or otherwise, without written permission from the Publisher

PREFACE

This series was organized to provide a forum for review papers in the area of corrosion. The aim of these reviews is to bring certain areas of corrosion science and technology into a sharp focus. The volumes of this series are published approximately on a yearly basis and each contains three to five reviews. The articles in each volume are selected in such a way as to be of interest both to the corrosion scientists and the corrosion technologists. There is, in fact, a particular aim in juxtaposing these interests because of the importance of mutual interaction and interdisciplinarity so important in corrosion studies. It is hoped that the corrosiori scientists in this way may stay abreast of the activities in corrosion technology and vice versa. In this series the term "corrosion" is used in its very broadest sense. It includes, therefore, not only the degradation of metals in aqueous environment but also what is commonly referred to as "high-temperature oxidation." Further, the plan is to be even more general than t