An Extended Approach on Power Conversion Efficiency Enhancement Through Deposition of ZnS-Al 2 S 3 Blends on Silicon Sol
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https://doi.org/10.1007/s11664-020-08361-x 2020 The Minerals, Metals & Materials Society
An Extended Approach on Power Conversion Efficiency Enhancement Through Deposition of ZnS-Al2S3 Blends on Silicon Solar Cells GOBINATH VELU KALIYANNAN ,1,5 SENTHIL VELMURUGAN PALANISAMY,1 RAJASEKAR RATHANASAMY,1 MANIVASAKAN PALANISAMY,2 NITHYAVATHY NAGARAJAN,3 SANTHOSH SIVARAJ,1 and MANJU SRI ANBUPALANI4 1.—Department of Mechanical Engineering, Kongu Engineering College, Perundurai, Tamil Nadu 638060, India. 2.—Department of Chemistry, Bharathiar University Arts and Science College, Modakurichi, Tamil Nadu 638104, India. 3.—Department of Mechatronics Engineering, Kongu Engineering College, Perundurai, Tamil Nadu 638060, India. 4.—Department of Chemical Engineering, Kongu Engineering College, Perundurai, Tamil Nadu 638060, India. 5.—e-mail: [email protected]
Transparent zinc sulfide (ZnS)-aluminium sulfide (Al2S3) composite thin-films are deposited on silicon solar cells through radio frequency (RF) sputtering method at room temperature to investigate the structural, optical, electrical, and thermal characteristics. X-ray diffraction analysis reveals the presence of the powder sample (ZnS-Al2S3) and its average crystallite size is 15.83 nm. The minimum electrical resistivity (q), maximum hall mobility (l), and carrier concentration (N) of ZnS-Al2S3 nano-layer coated solar cells are measured to be 2.98 9 103 X cm, 14.89 cm2 V1 s1 and 24.88 9 1020 cm3 respectively. For a time period of 25 min, ZnS-Al2S3 nano-layer sputter coating produces the maximum power conversion efficiencies (PCE) of 19.38% and 21%, obtained at open and controlled atmospheric conditions, respectively. The influence of operating temperature at both these open and controlled atmospheric conditions for ZnS-Al2S3 nano-layer coated silicon solar cells is observed. The ZnS-Al2S3 composite demonstrates the properties of a desirable anti-reflection coating material for enhancing the PCE of solar cells. Key words: Renewable energy, silicon solar cell, optical loss, anti-reflection coating, zinc sulfide-aluminium sulfide, power conversion efficiency
INTRODUCTION Renewable energy is a significant contributor to the achievement of basic energy policy.1 Photovoltaic energy is the most promising substitute for fossil fuels, owing to its clean energy production, among all the different sustainable renewable energy resources.2,3 A solar cell is an electrical
(Received March 17, 2020; accepted July 24, 2020; published online August 10, 2020)
device that converts light energy into electrical energy through the photovoltaic effect. The elementary material used for the fabrication of solar cells is silicon.4 High-performance polycrystalline silicon solar cells enhance the light transmittance characteristics with lower optical loss. The power conversion efficiency (PCE) of a silicon solar cell depends on its surface reflections. Anti-reflection coating (ARC) plays a key role in enhancing the PCE of solar cells by reducing the reflection losses in the solar cell.5,
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