Ba-Nd (Barium-Neodymium)

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Section III: Supplemental Literature Review

Ba-Nd (Barium-Neodymium) H. Okamoto

References

The Ba-Nd phase diagram in [Massalski2] was as assessed by [1988Gsc] based on limited experimental data and assumed similarity to other Ba-rare earth systems. Figure 1 shows the Ba-Nd phase diagram obtained by thermodynamic assessment by [2003Lys]. The width of the immiscibility gap between the liquid phases was estimated to be much broader in [Massalski2] in comparison with [2003Lys].

1988Gsc: K.A. Gschneidner, Jr. and F.W. Calderwood, The Ba-Nd (Barium-Neodymium) System, Bull. Alloy Phase Diagrams, 1988, 9(3), p 220-221 2003Lys: V.A. Lysenko, Thermodynamic Calculations of Phase Equilibria in the Barium-Copper-Neodymium System, Zh. Fiz. Khim., 2003, 77(9), p 1556-1560

Weight Percent Neodymium 0

10

20

30

40

50

60

70

80

90

100

1600

1500

1400

L2

L1 L1 + L2

Temperature, °C

1300

1200

1100 1013°C

1021°C

1000

L1 + (βNd) 900

(βNd)

858°C

863°C

L1 + (αNd)

800

(αNd)

727°C

727°C 700

(Ba) + (αNd)

(Ba) 600 0

Ba

10

20

30

40

50

60

70

80

90

Atomic Percent Neodymium

Fig. 1 Ba-Nd phase diagram

542

Journal of Phase Equilibria and Diffusion Vol. 29 No. 6 2008

100

Nd