Carbon@CoFe 2 O 4 @Ag and hollow CoFe 2 O 4 @Ag nanocomposite: green synthesis of a photocatalyst and magnetic adsorbent

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Carbon@CoFe2O4@Ag and hollow CoFe2O4@Ag nanocomposite: green synthesis of a photocatalyst and magnetic adsorbent for antibiotic removal from aqueous solutions Zahra Bodaghi1, Fatemeh Pakpour1,* 1

, and Davood Ghanbari1

Department of Science, Arak University of Technology, Arak, Iran

Received: 19 May 2020

ABSTRACT

Accepted: 5 September 2020

Nowadays antibiotics are one of the most widely used drugs with a high amount of release in nature and a major contribution to environmental pollution. Activated carbon is one of the most widespread adsorbents of these contaminants, but the main drawback to the use of this material is the difficulty of separation from the environment. In this study, we presented a straightforward and biocompatible method for preparation of carbon-based nanocomposite containing cobalt ferrite for use in wastewater treatment. Cobalt ferrite and silver nanoparticles were synthesized on the carbon templates by a hydrothermal method as a green procedure. In this work, grapefruit extract was used to make activated carbon powder. The prepared products were characterized by X-ray Diffraction pattern (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Ultraviolet–Visible absorption (UV–Vis), Energy Dispersive X-ray (EDX), and Fourier Transform Infrared spectroscopy (FT-IR). Vibrating Sample Magnetometer (VSM) was used to study the magnetic properties of the products. New magnetic C@CoFe2O4@Ag nanocomposite was successfully examined for removal of penicillin and ciprofloxacin from aqueous solutions. Because of the presence of silver on the C@CoFe2O4@Ag, it also showed photocatalyst property in the photo-degradation of organic pollutants.

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Springer Science+Business

Media, LLC, part of Springer Nature 2020

1 Introduction Over the last several decades, antibiotics have been the most common treatment of bacterial infections. Every year a huge amount of antibiotics is consumed either for fighting against pathogenic infections in

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https://doi.org/10.1007/s10854-020-04439-8

human bodies or animal farming and even plant growing [1–3]. Because of the wide range of antibiotic applications, a huge amount of these materials and their metabolites are exposed to the natural ecosystem. Thus, antibiotics can highly affect the biosphere and change the structure and activity of

J Mater Sci: Mater Electron

environmental microbiota [4]. Although antibiotics have been one of the great advances in medical science during last century, the extensive use of these drugs has resulted in the rise of a phenomenon known as antibiotic resistance [5]. Antibiotic resistance is considered as a serious threat to human health that can affect anyone at any age category in any place around the world and leads to increase of hospital stay and mortality rate [6]. So sewage treatment has turned to one of the most crucial human concerns in the present day. In recent years, several studies on environmental contaminants such as antibiotics, chemicals,