Chromium -VI Reagents: Synthetic Applications
Chromic acid and chromium oxide are the two versatile Cr(VI) oxidants known to organic chemists for decades. The introduction of the Core's reagent , viz: pyridinium chlorochromate, in 1975 followed by the publications on several Cr(VI) oxidizing agents c
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S. Sundaram P. S. Raghavan •
Chromium-VI Reagents: Synthetic Applications
123
Prof. S. Sundaram Department of Chemistry Ramakrishna Mission Vivekananda College Mylapore Chennai 600004 India
ISSN 2191-5407 ISBN 978-3-642-20816-4 DOI 10.1007/978-3-642-20817-1
Prof. P. S. Raghavan Department of Chemistry Madras Christian College Tambaram Chennai 600059 India e-mail: [email protected]
e-ISSN 2191-5415 e-ISBN 978-3-642-20817-1
Springer Heidelberg Dordrecht London New York Ó P. S. Raghavan 2011 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer. Violations are liable to prosecution under the German Copyright Law. The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Cover design: eStudio Calamar, Berlin/Figueres Printed on acid-free paper Springer is part of Springer Science+Business Media (www.springer.com)
Preface
Chromium (VI) reagents are versatile oxidants used frequently by both academic and industrial chemists. In the past three decades, particularly from 1975, a number of new oxidizing agents containing Cr(VI) species have been discovered and published in various professional journals. Such newly discovered Cr(VI) oxidants have been found to possess certain specificity and selectivity in their behaviour. All such interesting and useful informations from various international journals have been collected; the methods of preparation of these compounds and their applications in different spheres have been critically evaluated, and are presented in this book in such a manner that this would be an easy-to-use ready reconer for persons working in this field. This monograph is the ONLY COMPREHENSIVE SOURCE of information on as many as 40 new generation Cr(VI) reagents, in our opinion, this publication will be useful for post-graduate chemistry students of all colleges and universities and chemists working in the academic and industrial research laboratories world wide. The information presented in this book spans as many as 284 original research papers published in various international professional journals and, only very significant and specific data on each of the reagents considered are presented in this book. Though the main attention is on the synthetic applications of these reagents, their utility in the kinetics and biological application is also significant and are outl
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