Colloidal Transport in Porous Media

Colloids are known to be the often neglected phase for the transport of pollutants in aquatic ecosystems. The book covers the basics of abiotic colloid characterization, of biocolloids and biofilms, the resulting transport phenomena and their engineering

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Fritz H. Frimmel Frank von der Kammer Hans-Curt Flemming (Editors)

Colloidal Transport in Porous Media

With 99 Figures

PROF. DR. DR. HABIL. FRITZ H. FRIMMEL University of Karlsruhe Engler-Bunte-Institute Department of Water Chemistry Engler-Bunte-Ring 1 76131 Karlsruhe Germany Email: [email protected] DR. FRANK VON DER KAMMER University of Vienna Department of Geological Sciences Althanstraße 14 1090 Vienna Austria Email: [email protected] PROF. DR. HANS-CURT FLEMMING Faculty of Chemistry – Biofilm Centre University of Duisburg-Essen Geibelstraße 41 47057 Duisburg Germany Email: [email protected]

Library of Congress Control Number: 2007923066 ISBN-13

978-3-540-71338-8 Springer Berlin Heidelberg New York

This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable to prosecution under the German Copyright Law. Springer is a part of Springer Science+Business Media springer.com © Springer-Verlag Berlin Heidelberg 2007 The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Cover design: deblik, Berlin Typesetting: camera-ready by the editors Production: Christine Adolph Printing: Krips bv, Meppel Binding: Stürtz AG, Würzburg Printed on acid-free paper

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Preface Starting from the dimension of one or two meters which is typical for the size of human beings, we can easily discover the million fold up and down scales. However, three more digits in either direction are already a challenge for our perception, and we need sophisticated instrumental tools and analogy concepts to obtain an image of the material present. Therefore these domains have remained more unclear in many aspects of the properties and fate of the matter concerned. Particles in the smaller dimension more exactly of the size from 1 nanometer to 1 micrometer - are normally called colloids and have recently gained a renaissance of attention of physicists, chemists, material scientists and engineers. A broad application of tailored nano particles in the daily life has been the result. Also geogenic nano and micro particles and their important role in the transport and distribution of living and non-living matter in nature have gained awareness of the scientists. In contrast to the chemo-biological importance of these micro particles stands the limited knowledge about their structure, function and fate

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